(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate

ALDRICH/384313 - 98%

Synonym: (4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarboxylic acid dimethyl ester; Dimethyl (4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate

CAS Number: 37031-30-4
Empirical Formula (Hill Notation): C₉H₁₄O₆
Molecular Weight: 218.20
MDL Number: MFCD00040504
Linear Formula: C₉H₁₄O₆
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-384313-5G	5 g	$63.60 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	98%
bp	80-82 °C/0.1 mmHg (lit.)
density	1.19 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/C9H14O6/c1-9(2)14-5(7(10)12-3)6(15-9)8(11)13-4/h5-6H,1-4H3/t5-,6-/m0/s1
InChI key	ROZOUYVVWUTPNG-WDSKDSINSA-N
optical activity	[α]20/D +54°, neat
refractive index	n20/D 1.439 (lit.)
SMILES string	COC(=O)[C@H]1OC(C)(C)O[C@@H]1C(=O)OC

Application:	(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate can be used as a starting material for the synthesis of: • Deuterated 1-deoxy-D-xylose. • C-terminal peptide -oxo-aldehydes using Fmoc solid-phase peptide synthesis methodology (SPPS). • Bis-Weinreb amide, a key intermediate for the preparation of myo-inositol analog via ring-closing metathesis.
Application:	Valuable building block for TADDOL chiral auxiliaries, dipyridine ligands, and threitols.
General description:	(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate is a chiral reagent used in organic synthesis. It is prepared by the reaction-rectification process from D -tartrate, and 2,2-dimethoxypropane.{138]
Packaging:	5 g in glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	closed cup
Flash Point(C)	closed cup

Purity	98%
bp	80-82 °C/0.1 mmHg (lit.)
Density	1.19 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.439 (lit.)
UNSPSC	12352005

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