Chlorotrimethylsilane solution

ALDRICH/384410 - 1.0 M in THF

Synonym: Trimethylchlorosilane

CAS Number: 75-77-4
Empirical Formula (Hill Notation): C₃H₉ClSi
Molecular Weight: 108.64
MDL Number: MFCD00000502
Linear Formula: (CH₃)₃SiCl
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-384410-100ML	100 mL	$59.40 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	1.0 M in THF
density	0.88 g/mL at 25 °C
form	liquid
InChI	1S/C3H9ClSi/c1-5(2,3)4/h1-3H3
InChI key	IJOOHPMOJXWVHK-UHFFFAOYSA-N
Quality Level	100
SMILES string	C[Si](C)(C)Cl

Application:	Chlorotrimethylsilane (TMSCl) can be used as a reagent: • To synthesize allenylsilane via carbolithiation of conjugated enynes with aryllithium. • In the reductive coupling of aldehydes and ketones to produce corresponding 1,2 diols in the presence of zirconocene dichloride and magnesium. • To prepare 4,4′-bis(trimethylsilyl)bicyclohexyl-2,2′-diene from 1,3-cyclohexadiene by reductive disilylation reaction.
General description:	Chlorotrimethylsilane (TMSCl) is a silylating agent employed in the silylation of alcohols, amines, carboxylic acids, thiols, and other functional groups. Silyl group serves as a protecting group for these original functional groups.
Packaging:	100 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H302 - H314 - H335 - H351
Precautionary statements	P201 - P210 - P233 - P261 - P280 - P370 + P378
Hazard Codes	F,C
Risk Statements	11-14-19-35-37-40
Safety Statements	16-26-36/37/39-45
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 1
Flash Point(F)	-4.0 °F - closed cup
Flash Point(C)	-20 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH019

Density	0.88 g/mL at 25 °C
UNSPSC	12352302

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