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Di-(2-picolyl)amine

ALDRICH/385638 - 97%

Synonym: Bis(2-pyridylmethyl)amine

CAS Number: 1539-42-0
Empirical Formula (Hill Notation): C12H13N3
Molecular Weight: 199.25
EC Number: 216-266-8
MDL Number: MFCD00129044
Linear Formula: C12H13N3
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-385638-1G 1 g
 $45.30
1/EA		 Add To Favorites
45-385638-5G 5 g
 $138.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 385638-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 385638-5G

 

assay 97%
bp 139-141 °C/1 mmHg (lit.)
density 1.107 g/mL at 25 °C (lit.)
functional group amine
InChI 1S/C12H13N3/c1-3-7-14-11(5-1)9-13-10-12-6-2-4-8-15-12/h1-8,13H,9-10H2
InChI key KXZQYLBVMZGIKC-UHFFFAOYSA-N
Quality Level 100 
refractive index n20/D 1.578 (lit.)
SMILES string C(NCc1ccccn1)c2ccccn2
solubility water: soluble (partially miscible)(lit.)
Application: Di-(2-picolyl)amine can be used as:• A reactant to synthesize di(2-pyridylmethylamino)alkanoic esters using ω-iodoaliphatic carboxylic esters in the presence of triethylamine.
• A ligand to synthesize iron complexes of di-(2-picolyl)amine by treating with iron trichloride, which can be used to catalyze the direct hydroxylation of benzene to phenol.
• A reagent for the protection of carboxylic acids as carboxamides of bispicolylamine.
General description: Di-(2-picolyl)amine (DPA), a secondary amine containing two picolyl substituents, acts as a tridentate ligand due to its three donor nitrogen atoms. It is commonly used in coordination chemistry for the synthesis of binary, ternary, and binuclear complexes with various metal ions, including copper (Cu) and cadmium (Cd).
Packaging: 1, 5 g in glass bottle
Purity 97%
bp 139-141 °C/1 mmHg (lit.)
Density 1.107 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.578 (lit.)
UNSPSC 12352100

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