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AD-mix-α

ALDRICH/392758

Synonym: AD-mix-alpha

MDL Number: MFCD00191975
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-392758-10G 10 g
 $62.40
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45-392758-50G 50 g
 $214.00
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45-392758-250G 250 g
 $716.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 392758-250G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 392758-50G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 392758-10G

 

form powder
InChI 1S/C48H54N6O4/c1-5-29-27-53-21-17-31(29)23-43(53)45(35-15-19-49-41-13-11-33(55-3)25-39(35)41)57-47-37-9-7-8-10-38(37)48(52-51-47)58-46(44-24-32-18-22-54(44)28-30(32)6-2)36-16-20-50-42-14-12-34(56-4)26-40(36)42/h7-16,19-20,25-26,29-32,43-46H,5-6,17-18,21-24,27-28H2,1-4H3/t29-,30+,31-,32+,43-,44-,45-,46-/m1/s1
InChI key YUCBLVFHJWOYDN-PPIALRKJSA-N
Quality Level 200 
SMILES string CC[C@@H]1CN2CCC1CC2[C@H](Oc3nnc(O[C@@H](C4CC5CCN4C[C@@H]5CC)c6ccnc7ccc(OC)cc67)c8ccccc38)c9ccnc%10ccc(OC)cc9%10
Application: AD-mix-α has been used in the asymmetric dihydroxylation (AD) step of synthesizing (+)-enantiomeric form of a potent anti-inflammatory methyl picolinate alkaloid from methyl 5-bromopicolinate.
Application: Catalyst employed in the Sharpless Asymmetric Dihyroxylation of (E,E)- or (E,Z)-1,3-dienoates. Also used in the preparation of ß-hydroxy-γ-lactones from ß,γ-unsaturated esters.
Application: Reagent for Sharpless Asymmetric Dihydroxylation.
Components: Mixture contains:
(DHQ)2PHAL (Cat. No. 392723) 0.0016 mole
Potassium carbonate, powder 0.4988 mole
Potassium ferricyanide 0.4988 mole
Potassium osmate dihydrate 0.0007 mole
General description: Contains chiral ligand (DHQ)2PHAL
Packaging: 10, 50, 250 g in glass bottle
UNSPSC 12352005

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