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AD-mix-β

ALDRICH/392766

Synonym: AD-mix-beta

MDL Number: MFCD00198107
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-392766-10G 10 g
 $66.40
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45-392766-50G 50 g
 $217.00
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45-392766-250G 250 g
 $614.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material.

This image depicts SKU: 392766-250G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material.

This image depicts SKU: 392766-50G

 

form powder
InChI 1S/C48H54N6O4/c1-5-29-27-53-21-17-31(29)23-43(53)45(35-15-19-49-41-13-11-33(55-3)25-39(35)41)57-47-37-9-7-8-10-38(37)48(52-51-47)58-46(44-24-32-18-22-54(44)28-30(32)6-2)36-16-20-50-42-14-12-34(56-4)26-40(36)42/h7-16,19-20,25-26,29-32,43-46H,5-6,17-18,21-24,27-28H2,1-4H3/t29-,30-,31-,32-,43+,44+,45-,46-/m0/s1
InChI key YUCBLVFHJWOYDN-HVLQGHBFSA-N
Quality Level 100 
SMILES string CC[C@@H]1CN2CCC1CC2[C@H](Oc3nnc(O[C@@H](C4CC5CCN4C[C@@H]5CC)c6ccnc7ccc(OC)cc67)c8ccccc38)c9ccnc%10ccc(OC)cc9%10
Application: Catalyst employed in the Sharpless Asymmetric Dihyroxylation of (E,E)- or (E,Z)-1,3-dienoates. Also used in the preparation of ß-hydroxy-γ-lactones from ß,γ-unsaturated esters.
Application: Reagent for Sharpless Asymmetric Dihydroxylation.
General description: Contains chiral ligand (DHQD)2PHAL

AD-mix-β is an oxidant used for the enantioselective synthesis of 2-Hydroxy-5-methyl-3-hexanone.
Legal Information: Sold under license from Rhodia Pharma Solutions.
Other Notes: Mixture contains:
(DHQD)2PHAL (Cat. No. 392731) 0.0016 mole
Potassium carbonate, powder 0.4988 mole
Potassium ferricyanide 0.4988 mole
Potassium osmate dihydrate 0.0007 mole
Packaging: 10 g in glass bottle
Packaging: 50, 250 g in poly bottle
UNSPSC 12352005

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