Pyrrolidine
ALDRICH/394238 - ≥99.5%, purified by redistillation
Synonym: Tetrahydropyrrole; Tetramethyleneimine
CAS Number: 123-75-1
Empirical Formula (Hill Notation): C4H9N
Molecular Weight: 71.12
EC Number: 204-648-7
MDL Number: MFCD00005249
Linear Formula: C4H9N
Product Type: Chemical
| assay | ≥99.5% |
| autoignition temp. | 653 °F |
| density | 0.852 g/mL at 25 °C (lit.) |
| expl. lim. | 10.6 % |
| form | liquid |
| InChI | 1S/C4H9N/c1-2-4-5-3-1/h5H |
| InChI key | RWRDLPDLKQPQOW-UHFFFAOYSA |
| purified by | redistillation |
| Quality Level | 200  |
| refractive index | n |
| SMILES string | C1CCNC1 |
| solubility | water: miscible |
| vapor density | 2.45 (vs air) |
| vapor pressure | 128 mmHg ( 39 °C) |
| 49 mmHg ( 20 °C) |
| Application: | Pyrrolidine may be used in the following studies: • Synthesis of pyrrolidine derivatives of pyrimidine. • As a catalyst in the selective monoallylation of allylic alcohols. • To capture carbondioxide in a bubble column reactor using pyrrolidine aqueous solutions by gas–liquid absorption. |
| General description: | Pyrrolidine is a five membered cyclic amine. It is a nitrogen heterocycle that forms the nucleus of various bioactive molecules. It can be synthesized by reacting 1,4-diaminobutanes with acids. It behaves as a strong base in employed in certain homogeneous nonaqueous reactions. Its crystalline structure has been investigated. Its reaction on the Ge(100)-2×1 surface and Si(100)-2×1 surface has been investigated. Pyrrolidine has been found to be one of the component of volatile amine fraction in the brewing process. A study on the kinetics of pyrrolidinolysis of phthalimide (PTH) shows second- and third-order terms in the rate law. Biodegradation of pyrrolidine by Mycobacterium strains has been studied. |
| Packaging: | 1 L in Sure/Seal™ |
| Packaging: | 100 mL in Sure/Seal™ |
| Symbol |    GHS02,GHS05,GHS07 |
| Signal word | Danger |
| Hazard statements | H225 - H302 + H332 - H314 |
| Precautionary statements | P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
| Hazard Codes | F,C |
| Risk Statements | 11-20/22-35 |
| Safety Statements | 16-26-36/37/39-45 |
| RIDADR | UN 1922 8(3) / PGII |
| WGK Germany | WGK 1 |
| Flash Point(F) | 37.4 °F - closed cup |
| Flash Point(C) | 3 °C - closed cup |
| Purity | ≥99.5% |
| Density | 0.852 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |