1-(Bromoacetyl)pyrene
ALDRICH/394408 - 97%
Synonym: 2-
CAS Number: 80480-15-5
Empirical Formula (Hill Notation): C18H11BrO
Molecular Weight: 323.18
MDL Number: MFCD00191839
Linear Formula: C18H11BrO
Product Type: Chemical
| assay | 97% |
| form | solid |
| functional group | bromo |
| ketone | |
| InChI | 1S/C18H11BrO/c19-10-16(20 |
| InChI key | KAEDEGFCOPIKKM-UHFFFAOYSA |
| mp | 129-131 °C (lit.) |
| Quality Level | 100  |
| SMILES string | BrCC(=O)c1ccc2ccc3cccc4cc |
| Application: | 1-(Bromoacetyl)pyrene is suitable for use in the following studies: • As an initiator in the bulk polymerization of 2-ethyl-2-oxazoline to generate pyrene labelled poly(2-ethyl-2-oxazoline) (PETOX-py). • As a fluorophore in the generation of podand-type fluoroionophores with two pyrene moieties. • As a fluorescent labeling agent for the determination of okadaic acid toxin by HPLC with fluorescence detection. It may also be used in the following studies: • As a photoremovable protecting group for carboxylic acids and amino acids. • As a photoinitiator in the photopolymerization of styrene with methylmethacrylate. • As a reactant in the synthesis of potentially tetradentate pyrene appended ligands. • As a derivatizing agent of dialkyl phosphates (DAP) in the HPTLC method of quantitative determination of DAP in fruit juices. |
| General description: | 1-(Bromoacetyl)pyrene (BAP) is a pyrene derivative. It has been synthesized by reacting cupric bromide with 1-acetylpyrene. Studies suggest that the introduction of a bromoacetyl chromophoric moiety to pyrene drastically increases the photoinitiating efficiency of pyrenes. |
| Packaging: | 5 g in glass bottle |
| Symbol |  GHS05 |
| Signal word | Danger |
| Hazard statements | H314 - H413 |
| Precautionary statements | P280 - P305 + P351 + P338 - P310 |
| Hazard Codes | C |
| Risk Statements | 34 |
| Safety Statements | 22-26-36/37/39-45 |
| RIDADR | UN 1759 8 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 97% |
| mp | 129-131 °C (lit.) |
| UNSPSC | 12352100 |