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4-(Dimethylamino)phenyldiphenylphosphine

ALDRICH/395021 - 95%

Synonym: 4-(Dimethylamino)triphenylphosphine; 4-(Diphenylphosphino)-N,N-dimethyl-benzenamine; 4-(Diphenylphosphino)-N,N-dimethylaniline

CAS Number: 739-58-2
Empirical Formula (Hill Notation): C20H20NP
Molecular Weight: 305.35
MDL Number: MFCD00192068
Linear Formula: (CH3)2NC6H4P(C6H5)2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-395021-5G 5 g
 $209.00
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assay 95%
functional group phosphine
InChI 1S/C20H20NP/c1-21(2)17-13-15-20(16-14-17)22(18-9-5-3-6-10-18)19-11-7-4-8-12-19/h3-16H,1-2H3
InChI key GOEGBJDTWXTPHP-UHFFFAOYSA-N
mp 151-154 °C (lit.)
reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
SMILES string CN(C)c1ccc(cc1)P(c2ccccc2)c3ccccc3
Application: Catalyst for:
• Preparation of dicyano(aryl)cyclohexenecarboxylic acid esters via regioselective annulation
• Diastereoselective cycloaddition of styrenyl allenoates
• Interfacial carbonylation of methylbenzyl bromide
• Hydroformylation of octene

Reducing agent for selectivity of disulfide-internally linked peptide-nucleic acid cleavage
Packaging: 5 g in glass bottle
Purity 95%
mp 151-154 °C (lit.)
UNSPSC 12352116

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