Tris(4-fluorophenyl)phosphine
ALDRICH/395099 - 98%
Synonym: Tri-
CAS Number: 18437-78-0
Empirical Formula (Hill Notation): C18H12F3P
Molecular Weight: 316.26
MDL Number: MFCD00013553
Linear Formula: (FC6H4)3P
Product Type: Chemical
12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.
| assay | 98% |
| functional group | phosphine |
| greener alternative category | Aligned  , |
| greener alternative product characteristics | Catalysis Learn more about the Principles of Green Chemistry . |
| InChI | 1S/C18H12F3P/c19-13-1-7-1 |
| InChI key | GEPJPYNDFSOARB-UHFFFAOYSA |
| mp | 79-83 °C (lit.) |
| reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction |
| reaction type: Heck Reaction | |
| reaction type: Hiyama Coupling | |
| reaction type: Negishi Coupling | |
| reaction type: Sonogashira Coupling | |
| reaction type: Stille Coupling | |
| reaction type: Suzuki-Miyaura Coupling | |
| reagent type: ligand | |
| SMILES string | Fc1ccc(cc1)P(c2ccc(F)cc2) |
| sustainability | Greener Alternative Product |
| Application: | Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids. Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids  |
| General description: | We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. |
| Packaging: | 5 g in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315 - H319 - H335 |
| Precautionary statements | P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 98% |
| mp | 79-83 °C (lit.) |
| UNSPSC | 12352101 |