(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

ALDRICH/404438 - 98%

Synonym: (S,S)-Jacobsen’s ligand

CAS Number: 135616-36-3
Empirical Formula (Hill Notation): C₃₆H₅₄N₂O₂
Molecular Weight: 546.83
MDL Number: MFCD00191801
Linear Formula: [[(CH₃)₃C]₂C₆H₂-2-(OH)CH=N]₂C₆H₁₀
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-404438-5G	5 g	$288.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	98%
functional group	imine
InChI	1S/C36H54N2O2/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12/h17-22,29-30,39-40H,13-16H2,1-12H3/b37-21+,38-22+/t29-,30-/m0/s1
InChI key	FYNXDGNCEBQLGC-GTHUDTLPSA-N
mp	203-206 °C (lit.)
optical activity	[α]20/D +315 to 15°, c = 1 in methylene chloride
Quality Level	100
SMILES string	CC(C)(C)c1cc(C=N[C@H]2CCCC[C@@H]2N=Cc3cc(cc(c3O)C(C)(C)C)C(C)(C)C)c(O)c(c1)C(C)(C)C

Application:	(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine is a chiral salen-type ligand used for preparing Jacobsen′s catalyst suitable for enantioselective epoxidation of olefins lacking functional groups.
Legal Information:	Licensed through Research Corporation Technologies
Packaging:	1, 5 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	98%
mp	203-206 °C (lit.)
UNSPSC	12352116

Choose a favorite list for this item:

Catalog Number	Description	Price

		$

Please choose a list :

Continue Shopping

Returns/Order support

Please fill out the form below if you want to request order support from Krackeler Scientific.