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Vanadium(V) oxytriisopropoxide

ALDRICH/404926

Synonym: Triisopropoxyvanadium(V) oxide; VTIP; Vanadium(V) trisisopropoxide oxide

CAS Number: 5588-84-1
Empirical Formula (Hill Notation): C9H21O4V
Molecular Weight: 244.20
EC Number: 226-997-4
MDL Number: MFCD00015017
Linear Formula: OV(OCH(CH3)2)3
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-404926-1G 1 g
$45.80
1/EA
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45-404926-10G 10 g
$255.00
1/EA
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bp 80-82 °C/2 mmHg (lit.)
composition V, 20.3-21.4% titration (, by potassium permanganate)
density 1.035 g/mL at 25 °C (lit.)
form liquid
InChI 1S/3C3H7O.O.V/c3*1-3(2)4;;/h3*3H,1-2H3;;/q3*-1;;+3
InChI key DSGGJXAUQHKOGQ-UHFFFAOYSA-N
Quality Level 200 
reaction suitability core: vanadium
  reagent type: catalyst
refractive index n20/D 1.479 (lit.)
SMILES string CC(C)O[V](=O)(OC(C)C)OC(C)C
Application: Asymmetric Transfer Hydrogenation 
Application: Vanadium(V) oxytriisopropoxide is a building block for a series of neutral oxovanadium complexes containing both ethoxide and acetylacetonate ligands the complexes have potential biological relevance as well as uses in catalysis. Vanadium (V) oxytriisopropoxide (VOTP) may be used directly as a V precursor to dope TiO2 to form a high performance anode for lithium ion batteries.
General description: Vanadium(V) oxytriisopropoxide is a versatile liquid organometallic compound widely used as an effective solution and vapor deposition precursor, particularly in processes like chemical vapor deposition (CVD) and atomic layer deposition (ALD). Its high volatility and reactivity make it suitable for creating vanadium-based thin films, oxides, and coatings used in electronics, catalysis, and energy storage applications.
Packaging: 1, 10 g in glass bottle
bp 80-82 °C/2 mmHg (lit.)
Density 1.035 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.479 (lit.)
UNSPSC 12352103

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