1-Bromo-2,4,6-tri-tert-butylbenzene
ALDRICH/407097 - 97%
CAS Number: 3975-77-7
Empirical Formula (Hill Notation): C18H29Br
Molecular Weight: 325.33
MDL Number: MFCD00191861
Linear Formula: [(CH3)3C]3C6H2Br
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 407097-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 407097-5G
| assay | 97% |
| InChI | 1S/C18H29Br/c1-16(2,3)12- |
| InChI key | JOKZWHPYNRDCOA-UHFFFAOYSA |
| mp | 168-173 °C (lit.) |
| SMILES string | CC(C)(C)c1cc(c(Br)c(c1)C( |
| Application: | 1-Bromo-2,4,6-tri-tert-butylbenzene was used in the synthesis of bulky biarylphosphine ligand. This ligand was reported to participate in the Pd-catalyzed C-O cross-coupling of a wide range of aryl halides and phenols under milder conditions. It was used to investigate the effect on oligomerization of increased steric bulk in dimethylindium( |
| General description: | 1-Bromo-2,4,6-tri-tert-butylbenzene (2,4,6-tri-tert-butylbromobenzene) is a hindered aryl bromide. 1-Bromo-2,4,6-tri-tert-butylbenzene on reaction with phenylboronic acid yields α,α-dimethyl-β-phenyl hydrostyrene. |
| Packaging: | 1, 5 g in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315 - H319 - H335 |
| Precautionary statements | P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 97% |
| mp | 168-173 °C (lit.) |
| UNSPSC | 12352100 |