4-Methylmorpholine
ALDRICH/407704 - purified by redistillation, ≥99.5%
Synonym: NMM
CAS Number: 109-02-4
Empirical Formula (Hill Notation): C5H11NO
Molecular Weight: 101.15
EC Number: 203-640-0
MDL Number: MFCD00006175
Linear Formula: C5H11NO
Product Type: Chemical
| assay | ≥99.5% |
| bp | 115-116 °C/750 mmHg (lit.) |
| density | 0.92 g/mL at 25 °C (lit.) |
| form | liquid |
| InChI | 1S/C5H11NO/c1-6-2-4-7-5-3 |
| InChI key | SJRJJKPEHAURKC-UHFFFAOYSA |
| mp | −66 °C (lit.) |
| pH | 10.6 (20 °C, 50 g/L) |
| purified by | glass distillation |
| redistillation | |
| refractive index | n |
| SMILES string | CN1CCOCC1 |
| vapor density | >1 (vs air) |
| vapor pressure | 18 mmHg ( 20 °C) |
| Application: | 4-Methylmorpholine may be used in the preparation of N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfo |
| General description: | 4-Methylmorpholine is an economical cation useful for the preparation of morpholinium cation-based ionic liquids. The experimental FT-IR and FT-Raman spectra of 4-methylmorpholine has been recorded over the range 4000-400cm-1 and 3500-100cm-1 respectively. It undergoes fluorination with cobalt(III) fluoride to afford highly fluorinated morpholines, which were characterized by mass and NMR spectroscopy. |
| Packaging: | 1 L in Sure/Seal™ |
| Packaging: | 100 mL in Sure/Seal™ |
| Symbol |    GHS02,GHS05,GHS07 |
| Signal word | Danger |
| Hazard statements | H225 - H302 - H314 |
| Precautionary statements | P210 - P280 - P301 + P312 + P330 - P303 + P361 + P353 - P305 + P351 + P338 + P310 |
| Hazard Codes | F,C |
| Risk Statements | 11-22-34 |
| Safety Statements | 16-26-36/37/39-45 |
| RIDADR | UN 2535 8(3) / PGII |
| WGK Germany | WGK 1 |
| Flash Point(F) | 53.6 °F - DIN 51755 Part 1 |
| Flash Point(C) | 12 °C - DIN 51755 Part 1 |
| Purity | ≥99.5% |
| bp | 115-116 °C/750 mmHg (lit.) |
| mp | −66 °C (lit.) |
| Density | 0.92 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |