Tributylgermanium hydride
ALDRICH/409170 - 99%
Synonym: Tributylgermane
CAS Number: 998-39-0
Empirical Formula (Hill Notation): C12H28Ge
Molecular Weight: 244.99
MDL Number: MFCD00077987
Linear Formula: [CH3(CH2)3]3GeH
Product Type: Chemical
assay | 99% |
bp | 123 °C/20 mmHg (lit.) |
density | 0.949 g/mL at 25 °C (lit.) |
form | liquid |
InChI | 1S/C12H28Ge/c1-4-7-10-13( |
InChI key | KTSWILXIWHVQLR-UHFFFAOYSA |
reaction suitability | core: germanium |
reagent type: reductant | |
refractive index | n |
SMILES string | CCCC[GeH](CCCC)CCCC |
Application: | Efficient reducing agent for benzylic chlorides. |
General description: | Tributylgermanium hydride is a radical generating reagent. Reductive alkylation of active olefins with alkyl halides with tributylgermanium hydride was investigated in detail. |
Packaging: | 1 g in glass bottle |
Packaging: | Packaged in glass bottles |
Symbol | GHS05,GHS07 |
Signal word | Danger |
Hazard statements | H302 - H312 - H318 - H332 |
Precautionary statements | P280 - P305 + P351 + P338 |
Hazard Codes | Xn |
Risk Statements | 20/21/22-41 |
Safety Statements | 26-36 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | 235.4 °F - closed cup |
Flash Point(C) | 113 °C - closed cup |
Purity | 99% |
bp | 123 °C/20 mmHg (lit.) |
Density | 0.949 g/mL at 25 °C (lit.) |
Refractive Index | n |
UNSPSC | 12352103 |