4,N,N-Trimethylaniline

ALDRICH/41690 - catalyst grade (for peroxide polymerization), ≥98.5% (GC)

Synonym: 4-Dimethylaminotoluene; N,N-Dimethyl-p-toluidine

CAS Number: 99-97-8
Empirical Formula (Hill Notation): C₉H₁₃N
Molecular Weight: 135.21
EC Number: 202-805-4
MDL Number: MFCD00008316
Linear Formula: CH₃C₆H₄N(CH₃)₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-41690-100ML	100 mL	$63.70 1/EA		Add To Favorites
45-41690-500ML	500 mL	$146.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	≥98.5% (GC)
bp	211 °C (lit.)
	90-92 °C/10 mmHg (lit.)
density	0.936 g/mL at 20 °C
	0.937 g/mL at 25 °C (lit.)
expl. lim.	7 %
form	liquid
grade	catalyst grade (for peroxide polymerization)
InChI	1S/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3
InChI key	GYVGXEWAOAAJEU-UHFFFAOYSA-N
refractive index	n20/D 1.546 (lit.)
	n20/D 1.547
SMILES string	CN(C)c1ccc(C)cc1
vapor density	>1 (vs air)

Application:	• Charge-transfer complexes for redox polymerization: 4,N,N-Trimethylaniline used for on-demand amine/peroxide redox polymerization. This research offers a new perspective on the use of 4,N,N-Trimethylaniline in creating controlled polymer structures, which is crucial for various industrial and pharmaceutical applications (Garra et al., 2018).
Caution:	may discolor to yellowish-green on storage
General description:	4,N,N-Trimethylaniline is a N-methyl-N-alkylaniline. Its reaction with vinyl ether catalyzed by CuCl₂has been reported to afford tetrahydroquinolines. Its radical cation undergoes reaction with the anthracene radical anion and generation of electrogenerated chemiluminescence (ECL) has been observed.
Packaging:	100, 500 mL in glass bottle

Symbol	GHS06,GHS08
Signal word	Danger
Hazard statements	H301 + H311 - H330 - H373 - H412
Precautionary statements	P273 - P280 - P301 + P310 + P330 - P302 + P352 + P312 - P304 + P340 + P310 - P314
Hazard Codes	T
Risk Statements	23/24/25-33-52/53
Safety Statements	28-36/37-45-61
RIDADR	UN 2810 6.1 / PGIII
WGK Germany	WGK 3
Flash Point(F)	168.8 °F - closed cup
Flash Point(C)	76 °C - closed cup

Purity	≥98.5% (GC)
bp	211 °C (lit.); 90-92 °C/10 mmHg (lit.)
Density	0.936 g/mL at 20 °C; 0.937 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.546 (lit.); n20/D 1.547
UNSPSC	12352100

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