B-Iodo-9-BBN solution
ALDRICH/416908 - 1.0 M in hexanes
Synonym: 9-
CAS Number: 70145-42-5
Empirical Formula (Hill Notation): C8H14BI
Molecular Weight: 247.91
MDL Number: MFCD00192226
Linear Formula: C8H14BI
Product Type: Chemical
concentration | 1.0 M in hexanes |
density | 0.816 g/mL at 25 °C |
form | liquid |
InChI | 1S/C8H14BI/c10-9-7-3-1-4- |
InChI key | YAYIUFDUYUYPJC-OCAPTIKFSA |
SMILES string | IB1C2CCCC1CCC2 |
Application: | B-Iodo-9-BBN solution (1.0 M in hexanes) can be used as a Lewis acid in the selective synthesis of δ-keto esters via a Michael-type addition reaction to α,β-unsaturated ketones. |
General description: | B-Iodo-9-BBN is a boron-based organic compound that is commonly used as a reagent in organic synthesis for the iodoboration of alkynes, enolboration, the demethylation of phenol methyl ethers, and synthesis of boron-containing compounds. |
Packaging: | 25 mL in Sure/Seal™ |
Symbol | GHS02,GHS07,GHS08,GHS09 |
Signal word | Danger |
Hazard statements | H225 - H304 - H315 - H336 - H361f - H373 - H411 |
Precautionary statements | P201 - P210 - P273 - P301 + P310 + P331 - P302 + P352 - P308 + P313 |
Hazard Codes | F,Xn,N |
Risk Statements | 11-38-48/20-51/53-62-65-67 |
Safety Statements | 16-36/37-61-62 |
RIDADR | UN 2924 8(3) / PGII |
WGK Germany | WGK 3 |
Flash Point(F) | -9.4 °F - closed cup |
Flash Point(C) | -23 °C - closed cup |
Density | 0.816 g/mL at 25 °C |
UNSPSC | 12352101 |