Triphenylphosphine diiodide
ALDRICH/419184 - technical grade, 90%
Synonym: Diiodotriphenylphosphorane
CAS Number: 6396-07-2
Empirical Formula (Hill Notation): C18H15I2P
Molecular Weight: 516.09
MDL Number: MFCD00216568
Linear Formula: (C6H5)3PI2
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 419184-5G
| assay | 90% |
| form | solid |
| grade | technical grade |
| InChI | 1S/C18H15I2P/c19-21(20,16 |
| InChI key | NSWZEXJQHIXCFL-UHFFFAOYSA |
| mp | 210-220 °C (lit.) |
| SMILES string | IP(I)(c1ccccc1)(c2ccccc2) |
| Application: | Triphenylphosphine diiodide (Ph3P. I2) can be used as a reagent: • To facilitate the conversion of alcohol, thiol, and enol functional groups into alkyl iodides via formation of alkoxyphosphonium iodide. • To prepare β-iodo-α,β-unsaturated ketones from cyclic β-diketones in the presence of triethyl amine. • In the synthesis of alkyl nitrates from alcohols. • In the Beckmann rearrangement reaction to synthesize lactams from cycloalkanone oxime. • For the preparation of aromatic and aliphatic carboxylic acid esters in the presence of N,N-dimethylaminopyridine. Ph3P. I2 can also be used to reduce graphene oxide for the production of graphene nanosheets under mild and environmentally friendly conditions. |
| Packaging: | 5 g in glass bottle |
| Symbol |   GHS05,GHS08 |
| Signal word | Danger |
| Hazard statements | H314 - H317 - H334 - H361 |
| Precautionary statements | P201 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313 |
| Hazard Codes | C |
| Risk Statements | 34-42/43-62 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 2923 6.1(8) / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 90% |
| mp | 210-220 °C (lit.) |
| UNSPSC | 12352101 |