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Triphenylphosphine diiodide

ALDRICH/419184 - technical grade, 90%

Synonym: Diiodotriphenylphosphorane

CAS Number: 6396-07-2
Empirical Formula (Hill Notation): C18H15I2P
Molecular Weight: 516.09
MDL Number: MFCD00216568
Linear Formula: (C6H5)3PI2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-419184-5G 5 g
 $172.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 419184-5G

 

assay 90%
form solid
functional group phosphine
grade technical grade
InChI 1S/C18H15I2P/c19-21(20,16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
InChI key NSWZEXJQHIXCFL-UHFFFAOYSA-N
mp 210-220 °C (lit.)
Quality Level 100 
SMILES string IP(I)(c1ccccc1)(c2ccccc2)c3ccccc3
Application: Triphenylphosphine diiodide (Ph3P. I2) can be used as a reagent:
•  To facilitate the conversion of alcohol, thiol, and enol functional groups into alkyl iodides via formation of alkoxyphosphonium iodide.
•  To prepare β-iodo-α,β-unsaturated ketones from cyclic β-diketones in the presence of triethyl amine.
•  In the synthesis of alkyl nitrates from alcohols.
•  In the Beckmann rearrangement reaction to synthesize lactams from cycloalkanone oxime.
•  For the preparation of aromatic and aliphatic carboxylic acid esters in the presence of N,N-dimethylaminopyridine.

Ph3P. I2 can also be used to reduce graphene oxide for the production of graphene nanosheets under mild and environmentally friendly conditions.
Packaging: 5 g in glass bottle
Purity 90%
mp 210-220 °C (lit.)
UNSPSC 12352101

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