2-Methylallylmagnesium chloride solution

ALDRICH/419532 - 0.5 M in THF

Synonym: (2-Methyl-2-propenyl)magnesium chloride; Chloro(2-methyl-2-propenyl)magnesium; Chloro(2-methylallyl)magnesium; Methallylmagnesium chloride

CAS Number: 5674-01-1
Empirical Formula (Hill Notation): C₄H₇ClMg
Molecular Weight: 114.86
MDL Number: MFCD00674003
Linear Formula: H₂C=C(CH₃)CH₂MgCl
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-419532-4X25ML	25 mL	$220.00 4/EA	Add To Favorites
45-419532-100ML	100 mL	$220.00 1/EA	Add To Favorites

25 mL Sure/Seal™ Packaging

Properties
Descriptions
Safety Info.
Basic Data

bp	65-67 °C
concentration	0.5 M in THF
density	0.915 g/mL at 25 °C
InChI	1S/C4H7.ClH.Mg/c1-4(2)3;;/h1-2H2,3H3;1H;/q;;+1/p-1
InChI key	BJVFGWYBOLMUEM-UHFFFAOYSA-M
reaction suitability	reaction type: Grignard Reaction
SMILES string	CC(=C)C[Mg]Cl

Application:	2-Methylallylmagnesium chloride is a general Grignard reagent used in the synthesis of (−)-aplysin, acutumine, dimedol and allyldicyclopentadienyltitanium(III) complexes.
Legal Information:	Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Packaging:	4×25, 100 mL in Sure/Seal™
Packaging:	The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H261 - H302 - H314 - H335 - H351
Precautionary statements	P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
Hazard Codes	F,Xn
Risk Statements	11-14/15-19-36/37/38-40
Safety Statements	16-26-36/37-43
RIDADR	UN 3399A 4.3(3) / PGI
WGK Germany	WGK 3
Flash Point(F)	-5.8 °F - closed cup
Flash Point(C)	-21 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH019

bp	65-67 °C
Density	0.915 g/mL at 25 °C
UNSPSC	12352103

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