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Isopropenylmagnesium bromide solution

ALDRICH/419567 - 0.5 M in THF

Synonym: 1-Methylvinylmagnesium bromide; 1-Propen-2-ylmagnesium bromide; 2-Propen-2-ylmagnesium bromide; Bromo prop-1-en-2-yl magnesium; Bromo(isopropenylmagnesium); Isopropenylmagnesium bromide

CAS Number: 13291-18-4
Empirical Formula (Hill Notation): C3H5BrMg
Molecular Weight: 145.28
MDL Number: MFCD00192240
Linear Formula: CH2=C(CH3)MgBr
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-419567-100ML 100 mL
 $196.00
1/EA		 Add To Favorites
45-419567-800ML 800 mL
 $363.00
1/EA		 Add To Favorites

 

bp 67 °C
concentration 0.5 M in THF
density 0.935 g/mL at 25 °C
InChI 1S/C3H5.BrH.Mg/c1-3-2;;/h1H2,2H3;1H;/q;;+1/p-1
InChI key LFTYALBVGVNGLI-UHFFFAOYSA-M
reaction suitability reaction type: Grignard Reaction
SMILES string CC(=C)[Mg]Br
Application: Isopropenylmagnesium bromide (iPrMgBr) solution (0.5 M in THF) has been used in the Grignard reaction, a key step the in preparation of zofenoprilat and (S)-(−)-phosphonotrixin. It can also be used for the regioselective ring opening of an optically active epoxy alcohol in the total synthesis of (+)-desepoxyasperdiol.
Packaging: 100, 800 mL in Sure/Seal™
bp 67 °C
Density 0.935 g/mL at 25 °C
UNSPSC 12352103

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