3-Butenylmagnesium bromide solution

ALDRICH/419591 - 0.5 M in THF

Synonym: 1-(Bromomagnesium)-3-butene; 1-(Bromomagnesium)-3-butene; 1-Buten-4-ylmagnesium bromide; Bromo(but-3-enyl)magnesium; Bromo-3-buten-1-ylmagnesium

CAS Number: 7103-09-5
Empirical Formula (Hill Notation): C₄H₇BrMg
Molecular Weight: 159.31
MDL Number: MFCD00209554
Linear Formula: H₂C=CHCH₂CH₂MgBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-419591-100ML	100 mL	$442.00 1/EA	Add To Favorites
45-419591-800ML	800 mL	$1390.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

bp	65 °C
concentration	0.5 M in THF
density	0.937 g/mL at 25 °C
InChI	1S/C4H7.BrH.Mg/c1-3-4-2;;/h3H,1-2,4H2;1H;/q;;+1/p-1
InChI key	SMLLHQBZPPSOSR-UHFFFAOYSA-M
reaction suitability	reaction type: Grignard Reaction
SMILES string	Br[Mg]CCC=C

Application:	Synthetic building block that can undergo ring-formation reactions facilitated by ruthenium catalysts.
Application:	Used in a key diastereoselective step in the synthesis of (–)-muricatacin from _L-tartaric acid.
Packaging:	100, 800 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H260 - H302 - H314 - H335 - H336 - H351
Precautionary statements	P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Codes	F,Xn
Risk Statements	11-14/15-19-36/37/38-40
Safety Statements	16-26-36/37-43
RIDADR	UN 3399A 4.3(3) / PGI
WGK Germany	WGK 3
Flash Point(F)	-22.0 °F - closed cup
Flash Point(C)	-30 °C - closed cup
Supplemental Hazard Statements	EUH018 - EUH019

bp	65 °C
Density	0.937 g/mL at 25 °C
UNSPSC	12352103

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