1-Methyl-2-propenylmagnesium chloride solution

ALDRICH/420042 - 0.5 M in THF

CAS Number: 21969-32-4
Empirical Formula (Hill Notation): C₄H₇ClMg
Molecular Weight: 114.86
MDL Number: MFCD00216570
Linear Formula: H₂C=CHCH(CH₃)MgCl
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-420042-100ML	100 mL	$372.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

bp	67 °C
concentration	0.5 M in THF
density	0.917 g/mL at 25 °C
InChI	1S/C4H7.ClH.Mg/c1-3-4-2;;/h3-4H,1H2,2H3;1H;/q;;+1/p-1
InChI key	RTJGBPYEBKZQGE-UHFFFAOYSA-M
reaction suitability	reaction type: Grignard Reaction
SMILES string	CC([Mg]Cl)C=C

Application:	1-Methyl-2-propenylmagnesium chloride is a Grignard type allylating reagent that can be used for the preparation of corresponding homoallylic alcohols by reacting with various aldehydes. It can also be utilized in the synthesis of 3,4-dihydro-4-(1-methyl-2-propen-1-yl)-2(1H)-pyrimidinethione derivatives by treating with 2-mercaptopyrimidine.
Packaging:	100 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H261 - H302 - H314 - H335 - H351
Precautionary statements	P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
Hazard Codes	F,Xn
Risk Statements	11-14/15-19-36/37/38-40
Safety Statements	16-26-36/37-43
RIDADR	UN 3399BC 4.3(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	-4.0 °F - closed cup
Flash Point(C)	-20 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH019

bp	67 °C
Density	0.917 g/mL at 25 °C
UNSPSC	12352103

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