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N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine

ALDRICH/420697 - 96%

Synonym: N-(Methoxymethyl)-N-(trimethylsilylmethyl)-N-benzylamine; N-Benzyl-N-(methoxymethyl)trimethylsilylmethylamine; Benzyl(methoxymethyl)[(trimethylsilyl)methyl]amine

CAS Number: 93102-05-7
Empirical Formula (Hill Notation): C13H23NOSi
Molecular Weight: 237.41
MDL Number: MFCD00674005
Linear Formula: C6H5CH2N(CH2OCH3)CH2Si(CH3)3
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-420697-5G 5 g
 $45.60
1/EA		 Add To Favorites
45-420697-25G 25 g
 $149.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 420697-100G.

 

assay 96%
bp 76 °C/0.3 mmHg (lit.)
density 0.928 g/mL at 25 °C (lit.)
form liquid
functional group amine
  ether
  phenyl
InChI 1S/C13H23NOSi/c1-15-11-14(12-16(2,3)4)10-13-8-6-5-7-9-13/h5-9H,10-12H2,1-4H3
InChI key RPZAAFUKDPKTKP-UHFFFAOYSA-N
Quality Level 100 
refractive index n20/D 1.492 (lit.)
SMILES string COCN(Cc1ccccc1)C[Si](C)(C)C
Application: Forms azomethine ylides which readily undergo [3+2] cycloaddition to α,ß-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields.
Application: Reacted in asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines.
Packaging: 5, 25, 100 g in glass bottle
Purity 96%
bp 76 °C/0.3 mmHg (lit.)
Density 0.928 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.492 (lit.)
UNSPSC 12352116

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