N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
ALDRICH/420697 - 96%
Synonym: N-(Methoxymethyl)-N-
CAS Number: 93102-05-7
Empirical Formula (Hill Notation): C13H23NOSi
Molecular Weight: 237.41
MDL Number: MFCD00674005
Linear Formula: C6H5CH2N(CH2OCH3)CH2Si(CH3)3
Product Type: Chemical
assay | 96% |
bp | 76 °C/0.3 mmHg (lit.) |
density | 0.928 g/mL at 25 °C (lit.) |
form | liquid |
InChI | 1S/C13H23NOSi/c1-15-11-14 |
InChI key | RPZAAFUKDPKTKP-UHFFFAOYSA |
refractive index | n |
SMILES string | COCN(Cc1ccccc1)C[Si](C)(C |
Application: | Forms azomethine ylides which readily undergo [3+2] cycloaddition to α,ß-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields. |
Application: | Reacted in asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines. |
Packaging: | 5, 25, 100 g in glass bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H315 - H319 - H335 |
Precautionary statements | P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26 |
RIDADR | NA 1993 / PGIII |
WGK Germany | WGK 3 |
Flash Point(F) | 150.8 °F - closed cup |
Flash Point(C) | 66 °C - closed cup |
Purity | 96% |
bp | 76 °C/0.3 mmHg (lit.) |
Density | 0.928 g/mL at 25 °C (lit.) |
Refractive Index | n |
UNSPSC | 12352116 |