Ethyl cis-3-iodoacrylate
ALDRICH/423602 - 98%
CAS Number: 31930-36-6
Empirical Formula (Hill Notation): C5H7IO2
Molecular Weight: 226.01
MDL Number: MFCD00209584
Linear Formula: ICH=CHCO2C2H5
Product Type: Chemical
| assay | 98% |
| bp | 85 °C/20 mmHg (lit.) |
| density | 1.765 g/mL at 25 °C (lit.) |
| form | liquid |
| InChI | 1S/C5H7IO2/c1-2-8-5(7)3-4 |
| InChI key | AELYFQSZXFFNGP-ARJAWSKDSA |
| refractive index | n |
| SMILES string | [H]C(I)=C(/[H])C(=O)OCC |
| storage temp. | 2-8°C |
| Application: | Ethyl cis-3-iodoacrylate may be used in the synthesis of the following: • vinyl sulfides • (Z)-1-iodohept-1-en-3-ol • (E)-1-iodohept-1-en-3-ol • (Z)-β-iodoacrolein • 6-oxo-M1Guo |
| General description: | Ethyl cis-3-iodoacrylate (cis-ethyl-β-iodoacrylate, ethyl (Z)-β-iodoacrylate) is Z-vinyl iodide derivative. It is reported to be prepared from ethyl propiolate by treating with sodium iodide. Its Suzuki coupling reaction with cyclic vinyl boronic acids has been studied. |
| Packaging: | 1, 5 g in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315 - H319 - H335 |
| Precautionary statements | P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | 210.2 °F - closed cup |
| Flash Point(C) | 99 °C - closed cup |
| Purity | 98% |
| bp | 85 °C/20 mmHg (lit.) |
| Density | 1.765 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352100 |