Phenyl trifluoromethanesulfonate
ALDRICH/423939 - 98%
Synonym: Phenyl triflate
CAS Number: 17763-67-6
Empirical Formula (Hill Notation): C7H5F3O3S
Molecular Weight: 226.17
MDL Number: MFCD00192399
Linear Formula: C6H5SO3CF3
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 423939-5ML.
| assay | 98% |
| bp | 99-100 °C/60 mmHg (lit.) |
| density | 1.396 g/mL at 25 °C (lit.) |
| form | liquid |
| InChI | 1S/C7H5F3O3S/c8-7(9,10)14 |
| InChI key | GRJHONXDTNBDTC-UHFFFAOYSA |
| refractive index | n |
| SMILES string | FC(F)(F)S(=O)(=O)Oc1ccccc |
| Application: | Phenyl trifluoromethanesulfonate (phenyl triflate) may be used in the following studies: • As an arylating agent for the asymmetric α-arylation of ketones catalyzed by Pd(dba)2 and difluorphos. • As a reactant in the one pot synthesis of carbazoles by palladium-catalyzed N-arylation of anilines with phenyl triflate followed by oxidative coupling. • Synthesis of N-(2,6-diarylbenzoyl)anili • As an arylating agent in the synthesis of (R)-2-phenyl-2,3-dihydrofur |
| General description: | Phenyl trifluoromethanesulfonate (phenyl triflate) is an aryl fluorosulphonate. It has been synthesized by the reaction of phenol with fluorosulphonic anhydride. |
| Packaging: | 5 mL in glass bottle |
| Symbol |   GHS05,GHS06 |
| Signal word | Danger |
| Hazard statements | H301 + H311 - H314 |
| Precautionary statements | P270 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
| Hazard Codes | T |
| Risk Statements | 24/25-34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 2927 8(6.1) / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | 159.8 °F - closed cup |
| Flash Point(C) | 71 °C - closed cup |
| Purity | 98% |
| bp | 99-100 °C/60 mmHg (lit.) |
| Density | 1.396 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |