2,6-Dimethylphenylmagnesium bromide solution

ALDRICH/425508 - 1.0 M in THF

Synonym: 2,6-Xylylmagnesium bromide; Bromo(2,6-dimethylphenyl)magnesium

CAS Number: 21450-64-6
Empirical Formula (Hill Notation): C₈H₉BrMg
Molecular Weight: 209.37
MDL Number: MFCD00192083
Linear Formula: (CH₃)₂C₆H₃MgBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-425508-100ML	100 mL	$165.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

bp	65-67 °C
concentration	1.0 M in THF
density	0.998 g/mL at 25 °C
InChI	1S/C8H9.BrH.Mg/c1-7-4-3-5-8(2)6-7;;/h3-5H,1-2H3;1H;/q;;+1/p-1
InChI key	BIGUVDUZGAJWQK-UHFFFAOYSA-M
reaction suitability	reaction type: Grignard Reaction
SMILES string	Cc1cccc(C)c1[Mg]Br

Application:	2,6-Dimethylphenylmagnesium bromide can be used: • As an intermediate in the synthesis of dibutyl(5,10-dihydro-1,9-di-p-toluoyl-5-p-tolyldipyrrinato)tin(IV), which is further used in the preparation of zinc-based porphyrin. • As a substrate in the preparation of substituted fluorenes by reacting with 2-substituted arenesulfonates and dihaloarenes.
Packaging:	100, 800 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS06,GHS08
Signal word	Danger
Hazard statements	H225 - H261 - H302 - H314 - H331 - H335 - H351
Precautionary statements	P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
Hazard Codes	F,C
Risk Statements	11-14/15-19-34-37-40
Safety Statements	16-26-36/37/39-43-45
RIDADR	UN 3399BC 4.3(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	-2.2 °F - closed cup
Flash Point(C)	-19 °C - closed cup
Supplemental Hazard Statements	EUH019

bp	65-67 °C
Density	0.998 g/mL at 25 °C
UNSPSC	12352103

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