Holmium(III) trifluoromethanesulfonate
ALDRICH/425699 - 98%
Synonym: Holmium(III) triflate; Trifluoromethanesulfonic acid holmium(III) salt
CAS Number: 139177-63-2
Empirical Formula (Hill Notation): C3F9HoO9S3
Molecular Weight: 612.14
MDL Number: MFCD00209590
Linear Formula: (CF3SO3)3Ho
Product Type: Chemical
assay | 98% |
InChI | 1S/3CHF3O3S.Ho/c3*2-1(3,4 |
InChI key | DBPDCYACEYLEMY-UHFFFAOYSA |
reaction suitability | core: holmium |
reagent type: catalyst | |
SMILES string | [Ho+3].[O-]S(=O)(=O)C(F)( |
Application: | A water-tolerant Lewis acid used in the Aldol reaction of silyl enol ethers with aldehydes. |
Application: | Catalyst for: • Asymmetric alpha-amination • Diels-Alder reactions • Stereoselective cycloaddition reactions • Benzyl etherification • Acceleration of hydrogen-transfer reactions • Glycosylation |
Packaging: | 1 g in glass bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H315 - H319 - H335 |
Precautionary statements | P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 98% |
UNSPSC | 12161600 |