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Poly(vinylidene fluoride-co-hexafluoropropylene)

ALDRICH/427160 - average Mw ~400,000, average Mn ~130,000, pellets

Synonym: PVDF-HFP

CAS Number: 9011-17-0
MDL Number: MFCD00212573
Linear Formula: (-CH2CF2-)x[-CF2CF(CF3)-]y
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-427160-100G 100 g
$70.00
1/EA
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material.

This image depicts SKU: 427160-100G

 

density 1.77 g/mL at 25 °C
dielectric constant 9.4-10.6, 100 Hz (ASTM D 150)
form pellets
hardness 65-70 (Shore D, ASTM D 2240)
impact strength 12-20 ft-lb/in. (Izod, ASTM D 256, notched)
melt index 3.5-7.5 g/10 min (230°C/12.5kg)
mol wt average Mn ~130,000
  average Mw ~400,000
refractive index n20/D 1.41
SMILES string FC(F)=C.FC(F)=C(F)C(F)(F)F
transition temp brittleness temperature -62 °C (ASTM 2800)
  Tm 140-145 °C (ASTM D 3418)
viscosity 23,000-27,000 poise(230 °C) (100 sec-1; typical)(lit.)
Application: Owing to its high polarity, wettability by organic solvents, and relatively high ionic conductivity, PVDF-HFP is widely used as a polymer matrix to prepare gel polymer electrolytes for energy storage applications. For example, it can be used to enhance the performance of flexible solid-state supercapacitors.

It can be used to prepare superhydrophobic polymer nanocomposites. For example, PVDF-HFP- SiO2 composite can be used to enhance the thermochromism in regioregular poly(3-hexylthiophene), P3HT.

It can also be used to prepare lead-free piezoelectric flexible polymer composites for nanogenerators. PVDF-HFP can be preferred over other polymer matrices because of its higher solubility, greater free volume, and better mechanical strength.
Application: Wire and cable coatings, flexible and corrosion-resistant tubing, and liners for pipes and tanks.
Features and Benefits: Excellent thermal stability, chemical and abrasion resistance, impervious to UV degradation, self-extinguishing and retains properties on aging. Improved flexibility at subzero temperatures, stress crack resistance and elongation to break over poly(vinylidene fluoride).
General description: Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) is a hydrophobic crystalline copolymer with excellent properties such as good thermal stability, high polarity, ionic conductivity, and good solvent resistance.
Packaging: 100 g in poly bottle
Physical form: Crystalline, thermoplastic copolymer.
RIDADR NONH for all modes of transport
WGK Germany WGK 2
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Density 1.77 g/mL at 25 °C
Refractive Index n20/D 1.41
UNSPSC 12162002

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