1-Propynylmagnesium bromide solution

ALDRICH/429007 - 0.5 M in THF

Synonym: 1-Propyn-1-ylmagnesium bromide; Bromo(prop-1-yn-1-yl)magnesium; Bromo-1-propynylmagnesium

CAS Number: 16466-97-0
Empirical Formula (Hill Notation): C₃H₃BrMg
Molecular Weight: 143.26
MDL Number: MFCD00216588
Linear Formula: CH₃C≡CMgBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-429007-100ML	100 mL	$189.00 1/EA	Add To Favorites
45-429007-800ML	800 mL	$433.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

bp	65-67 °C
concentration	0.5 M in THF
density	0.941 g/mL at 25 °C
InChI	1S/C3H3.BrH.Mg/c1-3-2;;/h1H3;1H;/q;;+1/p-1
InChI key	YVJBCTFVENNIOV-UHFFFAOYSA-M
reaction suitability	reaction type: Grignard Reaction
SMILES string	CC#C[Mg]Br
storage temp.	2-8°C

Application:	Preparation of hydroxy enynes which underwent gold(I)-catalyzed benzannulation leading to tetrahydronaphthalenes.
General description:	1-Propynylmagnesiumbromide solution is 1-propynylmagnesium bromide in 0.5M tetrahydrofuran.1-propynylmagnesium bromide solution used as a Grignard reagent in chemical synthesis. This research reagent can be used for chemical and organic transformations. It is used as a regent in the conversion of [11C]CO2 to [11C] amides via Mitsunobu reaction.
Packaging:	100, 800 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H261 - H302 - H314 - H335 - H351
Precautionary statements	P201 - P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Codes	F,C
Risk Statements	11-14/15-19-34-37-40
Safety Statements	16-26-36/37/39-43-45
RIDADR	UN 3399A 4.3(3) / PGI
WGK Germany	WGK 3
Flash Point(F)	30.2 °F - closed cup
Flash Point(C)	-1 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH018 - EUH019

bp	65-67 °C
Density	0.941 g/mL at 25 °C
Storage Temp.	2-8°C
UNSPSC	12352103

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