Cerium(III) chloride

ALDRICH/429406 - AnhydroBeads^™, −10 mesh, ≥99.99% trace metals basis

Synonym: Cerium trichloride; Cerous chloride

CAS Number: 7790-86-5
Empirical Formula (Hill Notation): CeCl₃
Molecular Weight: 246.48
EC Number: 232-227-8
MDL Number: MFCD00010929
Linear Formula: CeCl₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-429406-5G	5 g	$173.00 1/EA		Add To Favorites
45-429406-25G	25 g	$495.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

application(s)	electroplating material synthesis precursor perovskite solar cells
assay	≥99.99% trace metals basis
density	3.97 g/mL at 25 °C (lit.)
form	beads
grade	synthesis grade
impurities	≤100.0 ppm Trace Rare Earth Analysis
InChI	1S/Ce.3ClH/h;3*1H/q+3;;;/p-3
InChI key	VYLVYHXQOHJDJL-UHFFFAOYSA-K
mp	848 °C (lit.)
particle size	−10 mesh
product line	AnhydroBeads^™
Quality Level	100
reaction suitability	core: cerium
	reagent type: catalyst
SMILES string	Cl[Ce](Cl)Cl

Application:	The role of dynamic ligand exchange in the oxidation chemistry of cerium (III): This study explores the redox chemistry of cerium, utilizing Cerium(III) chloride in oxidation reactions to understand its potential in various chemical transformations (JR Robinson et al., 2016 ). • Photocatalytic C- C bond cleavage and amination of cycloalkanols by cerium (III) chloride complex: Examines the photocatalytic properties of a cerium(III) chloride complex, used for C-C bond cleavage and amination, highlighting its potential in organic synthesis (JJ Guo et al., 2016 ). Dehydration, hydrolysis and oxidation of cerium chloride heptahydrate in air atmosphere: Investigates the behavior of hydrated forms of Cerium(III) chloride under varying conditions, contributing to understanding its stability and reactivity (S Xue et al., 2017 ).
General description:	Cerium(III) chloride is a non-toxic, water-tolerant, Lewis acid catalyst that imparts high regio-and chemoselectivity to various chemical transformations. It is widely used as an environmentally friendly acidic promoter in many synthetic organic reactions such as C-C bond formation reaction, transition metal catalyze dhydrogenation, and reduction of C-O double bond.
Legal Information:	AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC
Other Notes:	Scoring knife is required to open the ampoule
Packaging:	5, 25 g in ampule

Symbol	GHS05,GHS09
Signal word	Danger
Hazard statements	H314 - H410
Precautionary statements	P260 - P273 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
RIDADR	UN 3260 8 / PGIII
WGK Germany	WGK 2

Purity	≥99.99% trace metals basis
mp	848 °C (lit.)
Density	3.97 g/mL at 25 °C (lit.)
UNSPSC	12352302

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