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Cerium(III) chloride

ALDRICH/429406 - AnhydroBeads™, −10 mesh, ≥99.99% trace metals basis

Synonym: Cerium trichloride; Cerous chloride

CAS Number: 7790-86-5
Empirical Formula (Hill Notation): CeCl3
Molecular Weight: 246.48
EC Number: 232-227-8
MDL Number: MFCD00010929
Linear Formula: CeCl3
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-429406-5G 5 g
 $163.00
1/EA		 Add To Favorites
45-429406-25G 25 g
 $465.00
1/EA		 Add To Favorites

 

assay ≥99.99% trace metals basis
density 3.97 g/mL at 25 °C (lit.)
form beads
impurities ≤100.0 ppm Trace Rare Earth Analysis
InChI 1S/Ce.3ClH/h;3*1H/q+3;;;/p-3
InChI key VYLVYHXQOHJDJL-UHFFFAOYSA-K
mp 848 °C (lit.)
particle size −10 mesh
product line AnhydroBeads™
reaction suitability reagent type: catalyst
core: cerium
SMILES string Cl[Ce](Cl)Cl
Application:
  • The role of dynamic ligand exchange in the oxidation chemistry of cerium (III): This study explores the redox chemistry of cerium, utilizing Cerium(III) chloride in oxidation reactions to understand its potential in various chemical transformations (JR Robinson et al., 2016 ).
    • Photocatalytic C- C bond cleavage and amination of cycloalkanols by cerium (III) chloride complex: Examines the photocatalytic properties of a cerium(III) chloride complex, used for C-C bond cleavage and amination, highlighting its potential in organic synthesis (JJ Guo et al., 2016 ).
  • Dehydration, hydrolysis and oxidation of cerium chloride heptahydrate in air atmosphere: Investigates the behavior of hydrated forms of Cerium(III) chloride under varying conditions, contributing to understanding its stability and reactivity (S Xue et al., 2017 ).
General description: Cerium(III) chloride is a non-toxic, water-tolerant, Lewis acid catalyst that imparts high regio-and chemoselectivity to various chemical transformations. It is widely used as an environmentally friendly acidic promoter in many synthetic organic reactions such as C-C bond formation reaction, transition metal catalyze dhydrogenation, and reduction of C-O double bond.
Legal Information: AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC
Other Notes: Scoring knife is required to open the ampoule
Packaging: 5, 25 g in ampule
Purity ≥99.99% trace metals basis
mp 848 °C (lit.)
Density 3.97 g/mL at 25 °C (lit.)
UNSPSC 12352302

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