Triisopropylsilanethiol
ALDRICH/429937 - 97%
Synonym: 1,1,1-
CAS Number: 156275-96-6
Empirical Formula (Hill Notation): C9H22SSi
Molecular Weight: 190.42
MDL Number: MFCD00216593
Linear Formula: [(CH3)2CH]3SiSH
Product Type: Chemical
assay | 97% |
bp | 70-75 °C/2 mmHg (lit.) |
density | 0.887 g/mL at 25 °C (lit.) |
form | liquid |
InChI | 1S/C9H22SSi/c1-7(2)11(10, |
InChI key | CPKHFNMJTBLKLK-UHFFFAOYSA |
refractive index | n |
SMILES string | CC(C)[Si](S)(C(C)C)C(C)C |
General description: | Triisopropylsilanethiol compound (TIPS-SH) is an organosilicon compound. It is an effective alternative to H2S to prepare unsymmetrical dialkyl sulfides and alkanethiols. During radical reactions, it serves as a polarity reversal catalyst. Furthermore, it serves as a ligand in the Ziegler-Natta polymerization of ethylene. HSTIPS reagent used to prepare 9-BBN-derived alkyl and aryl boranes. |
Packaging: | 1, 5 g in glass bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H315 - H319 - H335 |
Precautionary statements | P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
RIDADR | UN 3334 |
WGK Germany | WGK 3 |
Flash Point(F) | 170.6 °F - closed cup |
Flash Point(C) | 77 °C - closed cup |
Purity | 97% |
bp | 70-75 °C/2 mmHg (lit.) |
Density | 0.887 g/mL at 25 °C (lit.) |
Refractive Index | n |
UNSPSC | 12352103 |