Triethylgermanium hydride

ALDRICH/429961 - 98%

Synonym: Triethylgermane

CAS Number: 1188-14-3
Empirical Formula (Hill Notation): C₆H₁₆Ge
Molecular Weight: 160.83
MDL Number: MFCD00077989
Linear Formula: (C₂H₅)₃GeH
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-429961-1G	1 g	$177.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	98%
bp	121-122 °C/20 mmHg (lit.)
density	0.994 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/C6H16Ge/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3
InChI key	LTLGQZPDSQYFSB-UHFFFAOYSA-N
reaction suitability	core: germanium
	reagent type: reductant
refractive index	n20/D 1.433 (lit.)
SMILES string	CC[GeH](CC)CC

Application:	Reagent undergoes hydrogermylation with alkyl propiolates to give triethylgermylacrylates.
General description:	Triethylgermanium hydride (Ge(C₂H₅)₃H) may be prepared by a three step process: • Ge(C₂H₅)₃Br reacted with Na to yield Ge₂(C₂H₅)₆ • Ge₂(C₂H₅)₆ treated with Li to form Ge(C₂H₅)₃Li • ammonolysis of Ge(C₂H₅)₃Li to give the end product, Ge(C₂H₅)₃H. 1
Packaging:	1 g in glass bottle
Packaging:	Packaged in glass bottles

Symbol	GHS02,GHS07
Signal word	Danger
Hazard statements	H225 - H302 + H312 + H332
Precautionary statements	P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P312
Hazard Codes	F,Xn
Risk Statements	11-20/21/22
Safety Statements	16-36
RIDADR	UN 1993BF 3 / PGII
WGK Germany	WGK 3
Flash Point(F)	46.4 °F - closed cup
Flash Point(C)	8 °C - closed cup

Purity	98%
bp	121-122 °C/20 mmHg (lit.)
Density	0.994 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.433 (lit.)
UNSPSC	12352202

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