Vinyl bromide solution

ALDRICH/434191 - 1.0 M in THF

Synonym: Bromoethylene

CAS Number: 593-60-2
Empirical Formula (Hill Notation): C₂H₃Br
Molecular Weight: 106.95
MDL Number: MFCD00000183
Linear Formula: CH₂=CHBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-434191-100ML	100 mL	$109.00 1/EA		Add To Favorites
45-434191-800ML	800 mL	$477.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	1.0 M in THF
density	0.927 g/mL at 25 °C
form	liquid
InChI	1S/C2H3Br/c1-2-3/h2H,1H2
InChI key	INLLPKCGLOXCIV-UHFFFAOYSA-N
SMILES string	BrC=C
storage temp.	2-8°C
vapor pressure	12.46 psi ( 55 °C)
	3.6 psi ( 20 °C)

Application:	Sequential Vinyl Radical Cyclization/Fixation of Carbon Dioxide through Electrochemical Reduction of Vinyl Bromide in the Presence of an Electron-Transfer Mediator: This study explores the electrochemical reduction of vinyl bromide with a focus on vinyl radical cyclization and carbon dioxide fixation (A Katayama, H Senboku, 2016 ). A Comparison of the Wavelength-Dependent Photochemical Reactions of Ozone with Vinyl Bromide and Fluoride in Argon Matrices: The study compares the photochemical reactions of vinyl bromide and fluoride with ozone, examining their behavior in argon matrices (BS Ault, 2021 ).
Application:	Vinyl bromide solution can be used as a precursor for stereoselective synthesis of chiral 2-vinyl-tetrahydronaphthalens via asymmetric reductive coupling. These chiral compounds are valuable building blocks for natural products, agrochemicals, and liquid crystals.
General description:	Vinyl bromide solution belongs to haloalkenes andis highly reactive due to the presence of an unsaturated vinyl group. It can provide flame retardancy to polymers or materials when incorporated into their structure. It is also a versatile building block for polymerization, addition reactions, substitution reactions, and cross-coupling reactions like Suzuki-Miyaura and Negishi reactions. It can be used to introduce radiolabel into molecules for medical imaging.
Packaging:	100, 800 mL in Sure/Seal™

Symbol	GHS02,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H302 - H319 - H335 - H336 - H350
Precautionary statements	P202 - P210 - P233 - P301 + P312 - P305 + P351 + P338 - P308 + P313
Hazard Codes	F,T
Risk Statements	45-11-19-36/37
Safety Statements	53-16-26-45
RIDADR	UN 1993A 3 / PGI
WGK Germany	WGK 3
Flash Point(F)	1.4 °F - closed cup
Flash Point(C)	-17 °C - closed cup
Supplemental Hazard Statements	EUH019

Density	0.927 g/mL at 25 °C
Storage Temp.	2-8°C
UNSPSC	12162002

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