Diethyl chloromalonate

ALDRICH/437786 - 95%

CAS Number: 14064-10-9
Empirical Formula (Hill Notation): C₇H₁₁ClO₄
Molecular Weight: 194.61
EC Number: 237-913-0
MDL Number: MFCD00009140
Linear Formula: ClCH(CO₂C₂H₅)₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-437786-5ML	5 mL	$113.00 1/EA	Add To Favorites
45-437786-25ML	25 mL	$275.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	95%
density	1.204 g/mL at 25 °C (lit.)
form	liquid
functional group	chloro
	ester
InChI	1S/C7H11ClO4/c1-3-11-6(9)5(8)7(10)12-4-2/h5H,3-4H2,1-2H3
InChI key	WLWCQKMQYZFTDR-UHFFFAOYSA-N
Quality Level	100
refractive index	n20/D 1.432 (lit.)
SMILES string	CCOC(=O)C(Cl)C(=O)OCC

General description:

Diethyl chloromalonate (Diethyl α-chloromalonate) is a 2-halo-1,3-dicarbonyl compound. It participates in K₂CO₃-catalyzed domino reactions (Michael alkylation, Mannich alkylation, and aldol alkylation) of salicylic aldehyde derivatives to afford functionalized 2,3-dihydrobenzofurans. It reacts with Cs₂CO₃ in the presence of elemental S₈ or Se_n to afford the corresponding diethyl thioxo- or selenoxomalonates, which can be trapped in situ with various 1,3-dienes.

Packaging:

5, 25 mL in glass bottle

Symbol	GHS05,GHS07,GHS09
Signal word	Danger
Hazard statements	H314 - H335 - H400
Precautionary statements	P261 - P273 - P280 - P305 + P351 + P338 - P310
Hazard Codes	C
Risk Statements	34-36/37
Safety Statements	26-27-28-36/37/39-45
RIDADR	UN3265 - class 8 - PG 2 - EHS - Corrosive liquid, acidic, organi
WGK Germany	WGK 3
Flash Point(F)	235.4 °F - closed cup
Flash Point(C)	113 °C - closed cup

Purity	95%
Density	1.204 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.432 (lit.)
UNSPSC	12352100

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