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(1R)-(−)-Menthyl acetate

ALDRICH/441058 - 98%

Synonym: (-)-Menthol acetate; (-)-Menthyl acetate; (-)-p-Menthyl acetate; (1R,2S,5R)-5-Methyl-2-(1-methylethyl)cyclohexanol acetate; Acetic acid (R)-menthyl ester; L-Menthyl acetate; l-(-)-Menthyl acetate; l-Menthol acetate

CAS Number: 2623-23-6
Empirical Formula (Hill Notation): C12H22O2
Molecular Weight: 198.30
EC Number: 220-076-0
MDL Number: MFCD00001482
Linear Formula: C12H22O2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-441058-25ML 25 mL
 $72.00
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45-441058-100ML 100 mL
 $213.00
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assay 98%
bp 229-230 °C (lit.)
density 0.92 g/mL at 25 °C (lit.)
form liquid
functional group ester
InChI 1S/C12H22O2/c1-8(2)11-6-5-9(3)7-12(11)14-10(4)13/h8-9,11-12H,5-7H2,1-4H3/t9-,11+,12-/m1/s1
InChI key XHXUANMFYXWVNG-ADEWGFFLSA-N
optical activity [α]20/D −81°, c = 8 in benzene
optical purity ee: 98% (GLC)
Quality Level 100 
refractive index n20/D 1.447 (lit.)
SMILES string CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(C)=O
Application:

  • RIFM fragrance ingredient safety assessment, menthyl acetate (isomer unspecified): This safety assessment covers the toxicity data on menthyl acetate, indicating low toxicity and providing a foundation for safe usage in fragrances and related products (AM Api et al., 2017 ).

  • The crystalline sponge method: MOF terminal ligand effects: This article discusses the inclusion of (1R)-(−)-menthyl acetate into Metal-Organic Frameworks (MOFs) and analyzes its interactions and structural integration (TR Ramadhar et al., 2015 ).

  • Engineering a Bacillus subtilis esterase for selective hydrolysis of d, l-menthyl acetate in an organic solvent-free system: This research engineered a variant of Bacillus subtilis esterase that shows enhanced selectivity and efficiency in the hydrolysis of d, l-menthyl acetate, suitable for industrial applications (J Qiao et al., 2023 ).
Packaging: 25, 100 mL in glass bottle
RIDADR NA 1993 / PGIII
WGK Germany WGK 2
Flash Point(F) 170.6 °F - closed cup
Flash Point(C) 77 °C - closed cup
Purity 98%
bp 229-230 °C (lit.)
Density 0.92 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.447 (lit.)
UNSPSC 12352108

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