(1S)-(+)-3-Carene

ALDRICH/441619 - 99%

Synonym: (+)-3-Carene; (1S)-3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene

CAS Number: 498-15-7
Empirical Formula (Hill Notation): C₁₀H₁₆
Molecular Weight: 136.23
EC Number: 207-856-6
MDL Number: MFCD00066417
Linear Formula: C₁₀H₁₆
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-441619-1G	1 g	$64.40 1/EA		Add To Favorites
45-441619-5G	5 g	$164.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	99%
bp	170-172 °C (lit.)
density	0.865 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/C10H16/c1-7-4-5-8-9(6-7)10(8,2)3/h4,8-9H,5-6H2,1-3H3/t8-,9+/m1/s1
InChI key	BQOFWKZOCNGFEC-BDAKNGLRSA-N
optical activity	[α]20/D +17°, neat
Quality Level	200
refractive index	n20/D 1.472 (lit.)
SMILES string	[H][C@@]12CC=C(C)C[C@]1([H])C2(C)C

Application:	(1S)-(+)-3-Carene has been used as a standard during the quantification of components in Lavandula stoechas essential oils by fast gas chromatography-mass spectrometry (FGC-EI/MS). It may be used as a starting material in the total synthesis of (+)-ingenol. It may also be used to synthesize (1S,3S,4S,6R)-3,7,7-trimethyl-4-morpholino-4-yl-bicyclo(4.1.0)heptano-3-ol, which can catalyze the addition of diethylzinc to different aldehydes with high enantioselectivity.
Application:	Chiral building block for the preparation of bicyclo[3.2.0]heptenes that are useful intermediates in the synthesis of (+)-lineatin and both enantiomers of capnellene. Has been converted to its corresponding allenyl allylic ether for studies of its thermal isomerization chemistry. Precursor to di(4-isocaranyl)borane, an asymmetric hydroboration reagent for olefins.
General description:	(1S)-(+)-3-Carene is a monoterpene.
Packaging:	1, 5 g in glass bottle

Symbol	GHS02,GHS07,GHS09
Signal word	Warning
Hazard statements	H226 - H317 - H410
Precautionary statements	P273 - P280 - P501
Hazard Codes	Xi,N
Risk Statements	10-43-50/53
Safety Statements	36/37-60-61
RIDADR	UN 2319 3 / PGIII
WGK Germany	WGK 3

Purity	99%
bp	170-172 °C (lit.)
Density	0.865 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.472 (lit.)
UNSPSC	12352205

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