Poly(3-hexylthiophene-2,5-diyl)
ALDRICH/445703 - regioregular
Synonym: P3HT
CAS Number: 104934-50-1
MDL Number: MFCD00217686
Linear Formula: (C10H14S)n
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 445703-1G
| conductivity | ~103 S/cm (when doped with iodine) |
| fluorescence | λex 443 nm; λem 568 nm in chloroform |
| greener alternative category | Enabling  , |
| greener alternative product characteristics | Design for Energy Efficiency Learn more about the Principles of Green Chemistry . |
| mol wt | average Mw 50,000-100,000 |
| mp | 238 °C |
| OPV device performance | ITO/NiO/P3HT/PC61BM/LiF/A • Short-circuit current density (Jsc): 11.3 mA/cm2 • Open-circuit voltage (Voc): 0.64 V • Fill Factor (FF): 0.69 • Power Conversion Efficiency (PCE): 5.16 % |
| ITO/PEDOT:PSS/P3HT:PC61BM (1:08)/Al • Short-circuit current density (Jsc): 9.5 mA/cm2 • Open-circuit voltage (Voc): 0.63 V • Fill Factor (FF): 0.68 • Power Conversion Efficiency (PCE): 5 % |
|
| orbital energy | HOMO 5 eV |
| LUMO 3 eV | |
| semiconductor properties | P-type (mobility=1E-4-1E-1 cm2/V·s) |
| sustainability | Greener Alternative Product |
| Application: | For the characterization and solid-state properties of this polymer, see J. Am. Chem. Soc. . |
| Application: | P3HT, an electron donor that acts as a semiconducting active layer in combination with an electron acceptor like fullerene derivative (6,6)-phenyl C61-butyric acid methylester (PCBM), can be used to fabricate bulk heterojunction (HJT) based organic solar cells (OSCs). Volatile organic compounds (VOCs)and electric sensor devices can be developed by using Langmuir-Schaefer (LS) films of P3HT and poly(3-octylthiophene)(P3 |
| Application: | Poly(3-hexylthiophene-2,5 |
| Application: | Rechargeable battery electrodes, electrochromic devices, chemical and optical sensors, light-emitting diodes, microelectrical amplifiers, field-effect transistors and non-linear optical materials. |
| Features and Benefits: | Greater than 90% head-to-tail regiospecific conformation. Good processibility, environmental stability and electroactivity. |
| General description: | Poly(3-hexylthiophene) (P3HT) is a regioregular semiconducting polymer. It is used in organic electronics primarily because of its regular end-to-end arrangement of side chain, which allows efficient p- p stacking of the conjugated backbones. On account of the alkyl side group, P3HT is rendered hydrophobic in neutral state. Solution-to-solid phase transformation and thin film formation of poly(3-hexylthiophene) (P3HT) was reported in a study. |
| General description: | Poly(3-hexylthiophene-2,5 |
| General description: | We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". Hole transport organic materials allow perfect energy level alignment with the absorber layer and therefore efficient charge collection, are prone to degradation in ambient conditions.Click here  for more information. |
| Legal Information: | Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc. |
| Packaging: | 1 g in glass bottle |
| Packaging: | Packaged in glass bottles |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315 - H319 - H335 |
| Precautionary statements | P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| mp | 238 °C; 238 °C |
| UNSPSC | 12352103 |