2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane
ALDRICH/447536 - 95%
Synonym: Tetramethylethylene chlorophosphite
CAS Number: 14812-59-0
Empirical Formula (Hill Notation): C6H12ClO2P
Molecular Weight: 182.59
MDL Number: MFCD00274239
Linear Formula: C6H12ClO2P
Product Type: Chemical
| assay | 95% |
| bp | 81.5-82 °C/13 mmHg (lit.) |
| density | 1.149 g/mL at 25 °C (lit.) |
| InChI | 1S/C6H12ClO2P/c1-5(2)6(3, |
| InChI key | WGPCXYWWBFBNSS-UHFFFAOYSA |
| Quality Level | 200 ![]() |
| reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction |
| reaction type: Heck Reaction | |
| reaction type: Hiyama Coupling | |
| reaction type: Negishi Coupling | |
| reaction type: Sonogashira Coupling | |
| reaction type: Stille Coupling | |
| reaction type: Suzuki-Miyaura Coupling | |
| reagent type: ligand | |
| refractive index | n |
| SMILES string | CC1(C)OP(Cl)OC1(C)C |
| Application: | 2-Chloro-4,4,5,5-tetramet • As a reagent for the phosphitylation of alcohols and heteroatomic nucleophiles, resulting in the formation of useful glycosyl donors and ligands. • As a phosphitylation reagent to derivatize lignin samples for 31P NMR analysis. |
| Packaging: | 1, 5 g in glass bottle |
| Symbol | GHS05 |
| Signal word | Danger |
| Hazard statements | H314 |
| Precautionary statements | P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 |
| Hazard Codes | C |
| Risk Statements | 14-34 |
| Safety Statements | 22-26-27-36/37/39-45 |
| RIDADR | UN 3265 8 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | 235.4 °F - closed cup |
| Flash Point(C) | 113 °C - closed cup |
| Supplemental Hazard Statements | EUH014 |
| Purity | 95% |
| bp | 81.5-82 °C/13 mmHg (lit.) |
| Density | 1.149 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352005 |


