Borane diphenylphosphine complex
ALDRICH/449563 - 98%
Synonym: (Diphenylphosphine)
CAS Number: 41593-58-2
Empirical Formula (Hill Notation): C12H14BP
Molecular Weight: 200.02
MDL Number: MFCD00274254
Linear Formula: (C6H5)2PH·BH3
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 449563-5G
| assay | 98% |
| bp | 148-150 °C/10 mmHg (lit.) |
| form | solid |
| functional group | phosphine |
| InChI | 1S/C12H11P.BH3/c1-3-7-11( |
| InChI key | XUFGOLYVDOBYLK-UHFFFAOYSA |
| mp | 47-50 °C (lit.) |
| Quality Level | 100  |
| reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction |
| reaction type: Heck Reaction | |
| reaction type: Hiyama Coupling | |
| reaction type: Negishi Coupling | |
| reaction type: Sonogashira Coupling | |
| reaction type: Stille Coupling | |
| reaction type: Suzuki-Miyaura Coupling | |
| reagent type: ligand reaction type: Reductions |
|
| reagent type: reductant | |
| SMILES string | B.[H]P(c1ccccc1)c2ccccc2 |
| Application: | Reactant for: • Nucleophilic addition reactions (anion) • Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxes • Deprotonation reactions • Catalytic coupling with alkynyl bromides • Catalyst-free Staudinger ligation for indirect 18F-radiolabeling • Preparation of chiral phosphine-phosphite bidentate ligands with biphenyl backbone • Reactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases |
| Packaging: | 1, 5 g in glass bottle |
| Symbol |  GHS02 |
| Signal word | Danger |
| Hazard statements | H261 |
| Precautionary statements | P231 + P232 - P422 |
| Hazard Codes | F |
| Risk Statements | 15 |
| Safety Statements | 43 |
| RIDADR | UN 2813 4.3 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 98% |
| bp | 148-150 °C/10 mmHg (lit.) |
| mp | 47-50 °C (lit.) |
| UNSPSC | 12352002 |