(+)-Bis[(R)-1-phenylethyl]amine
ALDRICH/452823 - 99%
Synonym: (+)-Bis[(R)-α-methylbenzyl]amine; [R-(R*,R*)]-(+)-Bis(α-methylbenzyl)amine
CAS Number: 23294-41-9
Empirical Formula (Hill Notation): C16H19N
Molecular Weight: 225.33
MDL Number: MFCD00243088
Linear Formula: [C6H5CH(CH3)]2NH
Product Type: Chemical
| assay | 99% |
| bp | 86 °C/0.05 mmHg (lit.) |
| density | 0.985 g/mL at 25 °C (lit.) |
| InChI | 1S/C16H19N/c1-13(15-9-5-3 |
| InChI key | NXLACVVNHYIYJN-ZIAGYGMSSA |
| optical activity | [α]20/D +199.0°, neat |
| optical purity | ee: ≥99% (GLC) |
| refractive index | n |
| SMILES string | C[C@@H](N[C@H](C)c1ccccc1 |
| Application: | (+)-Bis[(R)-1-phenylethyl]amine can be used: • In the synthesis of β-amino acids. • In the preparation of chiral C(19)-C(26) and C(27)-C(32) moieties of scytophycin C. • To induce enantioselectivity in the deprotonation of prochiral ketones. • As a starting material for the synthesis of chiral phenolate ligands through Mannich condensation reaction. • In the synthesis of chiral phosphoramidite ligands. • To prepare chiral cyclic isoimidium salts, which are further used to synthesize chiral lactones through Diels-Alder reaction. |
| Packaging: | 1, 10 g in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315 - H319 - H335 |
| Precautionary statements | P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36/37 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | > 235.4 °F - closed cup |
| Flash Point(C) | > 113 °C - closed cup |
| Purity | 99% |
| bp | 86 °C/0.05 mmHg (lit.) |
| Density | 0.985 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352116 |