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Nickel(II) bromide 2-methoxyethyl ether complex

ALDRICH/459674

Synonym: Diglyme nickel dibromide

CAS Number: 312696-09-6
Empirical Formula (Hill Notation): C6H14Br2NiO3
Molecular Weight: 352.67
MDL Number: MFCD00274339
Linear Formula: NiBr2 · O(CH2CH2OCH3)2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-459674-5G 5 g
 $116.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 459674-5G

 

form powder
InChI 1S/C6H14O3.2BrH.Ni/c1-7-3-5-9-6-4-8-2;;;/h3-6H2,1-2H3;2*1H;/q;;;+2/p-2
InChI key RRSIMIHTHWYRRA-UHFFFAOYSA-L
reaction suitability reagent type: catalyst
core: nickel
SMILES string Br[Ni]Br.COCCOCCOC
Application: Nickel(II) bromide 2-methoxyethyl ether complex can be used as a catalyst to prepare:
• Hindered diarylmethanols and benzylic alcohols by the addition of aryl halides to various aldehydes in the presence of Zn as a reducing agent.
• Benzene-fused cyclic compounds via reductive dicarbofunctionalization of unactivated alkenes using less reactive benzyl chlorides.
• Benzylboron derivatives via C-C cross-coupling reaction between substituted 5-bromo-3-methoxy-2-(trimethylsilyl)phenyl triflate and bromomethylboronic acid pinacol ester.
• N-(Hetero)aryl sulfamides by N-arylation of sulfamides with aryl bromides in the presence of a photosensitizer.
Packaging: 5 g in glass bottle
UNSPSC 12352302

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