Nickel(II) bromide 2-methoxyethyl ether complex
ALDRICH/459674
Synonym: Diglyme nickel dibromide
CAS Number: 312696-09-6
Empirical Formula (Hill Notation): C6H14Br2NiO3
Molecular Weight: 352.67
MDL Number: MFCD00274339
Linear Formula: NiBr2 · O(CH2CH2OCH3)2
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 459674-5G
| application(s) | battery precursors catalysts material synthesis precursor |
| form | powder |
| InChI | 1S/C6H14O3.2BrH.Ni/c1-7-3 |
| InChI key | RRSIMIHTHWYRRA-UHFFFAOYSA |
| Quality Level | 100  |
| reaction suitability | core: nickel |
| reagent type: catalyst | |
| SMILES string | Br[Ni]Br.COCCOCCOC |
| Application: | Nickel(II) bromide 2-methoxyethyl ether complex can be used as a catalyst to prepare: • Hindered diarylmethanols and benzylic alcohols by the addition of aryl halides to various aldehydes in the presence of Zn as a reducing agent. • Benzene-fused cyclic compounds via reductive dicarbofunctionalization of unactivated alkenes using less reactive benzyl chlorides. • Benzylboron derivatives via C-C cross-coupling reaction between substituted 5-bromo-3-methoxy-2-(trim • N-(Hetero)aryl sulfamides by N-arylation of sulfamides with aryl bromides in the presence of a photosensitizer. |
| Packaging: | 5 g in glass bottle |
| Symbol |   GHS02,GHS07 |
| Signal word | Danger |
| Hazard statements | H228 - H302 + H312 + H332 - H315 - H319 - H335 |
| Precautionary statements | P210 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 |
| Hazard Codes | F,Xn |
| Risk Statements | 11-20/21/22-36/37/38 |
| Safety Statements | 26-36/37 |
| RIDADR | UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., H |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| UNSPSC | 12352302 |