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1,2-Bis(diphenylphosphino)benzene

ALDRICH/460273 - 97%

Synonym: 1,2-Bis(diphenylphosphanyl)benzene; dppBz; dppbe; dppben; dppbenz; dppbz; o-Phenylenebis[diphenylphosphine]; o-bis(diphenylphosphino)benzene

CAS Number: 13991-08-7
Empirical Formula (Hill Notation): C30H24P2
Molecular Weight: 446.46
MDL Number: MFCD00014081
Linear Formula: C6H4[P(C6H5)2]2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-460273-1G 1 g
 $90.70
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assay 97%
form solid
functional group phosphine
InChI 1S/C30H24P2/c1-5-15-25(16-6-1)31(26-17-7-2-8-18-26)29-23-13-14-24-30(29)32(27-19-9-3-10-20-27)28-21-11-4-12-22-28/h1-24H
InChI key NFRYVRNCDXULEX-UHFFFAOYSA-N
mp 183-188 °C (lit.)
reaction suitability reagent type: ligand
reaction type: Baeyer-Villiger Oxidation
  reagent type: ligand
reaction type: Cycloadditions
  reagent type: ligand
reaction type: Reductions
SMILES string c1ccc(cc1)P(c2ccccc2)c3ccccc3P(c4ccccc4)c5ccccc5
Application: 1,2-Bis(diphenylphosphino)benzene (DPPB) can be used:
• As a chelating ligand in the synthesis of luminescent copper(I) halide complexes.
• In the synthesis of copper-1,2-bis(diphenylphosphino)benzene catalyst which is used for the β-boration of α, β-unsaturated amide.
• As an alternative to TMEDA for the selective cleavage of sp3 C-X bond in fluoroaromatic coupling reactions catalyzed by iron.
• As a ligand in the synthesis of alkenylboronates from acetylenic esters.
• To synthesize copper-diphosphine complexes which are used as homogeneous catalysts for N-formylation of a wide range of amines.
Packaging: 1 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 97%
mp 183-188 °C (lit.)
UNSPSC 12352002

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