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Lithium diphenylphosphide solution

ALDRICH/464872 - 0.5 M in THF

Synonym: Diphenyl lithium phosphide; Diphenylphosphine lithium salt; Diphenylphosphino)lithium; Lithiodiphenyl phosphide; Lithiodiphenylphosphine

CAS Number: 65567-06-8
Empirical Formula (Hill Notation): C12H10LiP
Molecular Weight: 192.12
MDL Number: MFCD00046054
Linear Formula: (C6H5)2PLi
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-464872-100ML 100 mL
 $297.00
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bp 65-67 °C
concentration 0.5 M in THF
density 0.925 g/mL at 25 °C
InChI 1S/C12H10P.Li/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1
InChI key WKUYEGHEUWHKIU-UHFFFAOYSA-N
Quality Level 100 
reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
SMILES string [Li]P(c1ccccc1)c2ccccc2
Packaging: 100 mL in Sure/Seal™
Symbol GHS02GHS05GHS07GHS08GHS09  GHS02,GHS05,GHS07,GHS08,GHS09
Signal word Danger
Hazard statements H225 - H302 + H332 - H314 - H335 - H351 - H410
Precautionary statements P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
Hazard Codes F,C,N
Risk Statements 11-19-34-37-40-50/53
Safety Statements 16-26-36/37/39-45-61
RIDADR UN2924 - class 3 - PG 2 - EHS - basic - Flammable liquids, corro
WGK Germany WGK 2
Flash Point(F) -4.0 °F - closed cup
Flash Point(C) -20 °C - closed cup
Supplemental Hazard Statements EUH019
bp 65-67 °C
Density 0.925 g/mL at 25 °C
UNSPSC 12352002

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