Triethylsilane
ALDRICH/467448 - 97%
Synonym: NSC 93579; Triethylhydrosilane; Triethylsilicon hydride
CAS Number: 617-86-7
Empirical Formula (Hill Notation): C6H16Si
Molecular Weight: 116.28
EC Number: 210-535-3
MDL Number: MFCD00009018
Linear Formula: (C2H5)3SiH
Product Type: Chemical
assay | 97% |
bp | 107-108 °C (lit.) |
density | 0.728 g/mL at 25 °C (lit.) |
InChI | 1S/C6H16Si/c1-4-7(5-2)6-3 |
InChI key | AQRLNPVMDITEJU-UHFFFAOYSA |
reaction suitability | reagent type: reductant |
refractive index | n |
SMILES string | CC[SiH](CC)CC |
Application: | Catalyst for: • Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain • Redox initiated cationic polymerization • Beckmann rearrangement of cyclododecanone oxime • Regioselective reductive coupling of enones and allenes Catalyst reactivation after catalyst polymerization of styrene Studies involving the prediction of organosilicon flash points |
Application: | Triethylsilane can be used as: • A reducing agent in the regioselective reductive coupling of enones and allenes. • A reagent in the redox initiated cationic polymerization. • A reagent in catalytic transfer hydrogenation, reduction of alkyl halides and silylation of aromatic C-H bonds, etc. • As a reagent for the generation of indium hydride (Cl2InH) applicable as a catalyst for the intramolecular cyclization of enynes. |
Packaging: | 25, 100 mL in Sure/Seal™ |
Symbol | GHS02,GHS07 |
Signal word | Danger |
Hazard statements | H225 - H315 - H319 - H335 |
Precautionary statements | P210 - P302 + P352 - P305 + P351 + P338 |
Hazard Codes | F |
Risk Statements | 11-52/53 |
Safety Statements | 9-16-29-33-61 |
RIDADR | UN 1993BF 3 / PGII |
WGK Germany | WGK 1 |
Flash Point(F) | 21.2 °F |
Flash Point(C) | -6 °C |
Purity | 97% |
bp | 107-108 °C (lit.) |
Density | 0.728 g/mL at 25 °C (lit.) |
Refractive Index | n |
UNSPSC | 12352103 |