Tetrakis(dimethylamido)titanium(IV)

ALDRICH/469858 - 99.999% trace metals basis

Synonym: TDMAT; Tetrakis(dimethylamino)titanium(IV)

CAS Number: 3275-24-9
Empirical Formula (Hill Notation): C₈H₂₄N₄Ti
Molecular Weight: 224.17
EC Number: 221-904-3
MDL Number: MFCD00014861
Linear Formula: [(CH₃)₂N]₄Ti
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-469858-5G	5 g	$247.00 1/EA		Add To Favorites
45-469858-25G	25 g	$717.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	99.999% trace metals basis
bp	50 °C/0.5 mmHg (lit.)
density	0.947 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/4C2H6N.Ti/c41-3-2;/h41-2H3;/q4*-1;+4
InChI key	MNWRORMXBIWXCI-UHFFFAOYSA-N
Quality Level	200
reaction suitability	core: titanium
SMILES string	CN(C)[Ti](N(C)C)(N(C)C)N(C)C

Application:	Tetrakis(dimethylamido)titanium(IV) (TDMAT) is a precursor to titanium nitride (TiN) thin films by organometallic chemical vapor deposition (OMCVD)and titanium dioxide thin films by atomic layer deposition (ALD).TDMAT undergoes exothermal reaction with excess cyclopentadiene to yield tris(dimethylamido)(η5-cyclopentadienyl)titanium(IV).
General description:	Please inquire for bulk quantity, pricing, and packaging options.
Packaging:	5, 25 g in ampule

Symbol	GHS02,GHS05
Signal word	Danger
Hazard statements	H225 - H260 - H314
Precautionary statements	P210 - P223 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Codes	F,C
Risk Statements	11-14-34
Safety Statements	16-26-36/37/39-43-45
RIDADR	UN3398 - DOT UN3399 class 4.3 - PG 1 - Organometallic substance,
WGK Germany	WGK 3
Flash Point(F)	-22.0 °F - closed cup
Flash Point(C)	-30 °C - closed cup
Supplemental Hazard Statements	EUH014

Purity	99.999% trace metals basis
bp	50 °C/0.5 mmHg (lit.)
Density	0.947 g/mL at 25 °C (lit.)
UNSPSC	12352103

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