4-Methoxyphenylmagnesium bromide solution

ALDRICH/470260 - 0.5 M in THF

Synonym: (4-Methoxyphenyl)magnesium bromide; 4-Anisylmagnesium bromide; p-Methoxyphenylmagnesium bromide; Bromo(4-methoxyphenyl)magnesium

CAS Number: 13139-86-1
Empirical Formula (Hill Notation): C₇H₇BrMgO
Molecular Weight: 211.34
MDL Number: MFCD00013515
Linear Formula: CH₃OC₆H₄MgBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-470260-100ML	100 mL	$108.00 1/EA	Add To Favorites
45-470260-1L	1 L	$332.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

bp	65-67 °C
concentration	0.5 M in THF
density	0.955 g/mL at 25 °C
InChI	1S/C7H7O.BrH.Mg/c1-8-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1
InChI key	JKXAZEXIOPFJSC-UHFFFAOYSA-M
reaction suitability	reaction type: Grignard Reaction
SMILES string	COc1ccc([Mg]Br)cc1

Application:	4-Methoxyphenylmagnesium bromide is a general Grignard reagent that can be used: • In the denickelation of porphyrins and to replace the metal center with magnesium. • To synthesize a tubulin polymerization inhibitor, 2-Amino-3,4,5-trimethoxybenzophenone. • In the total synthesis of (−)-centrolobine.
Packaging:	1 L in Sure/Seal™
Packaging:	100 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H302 - H314 - H335 - H336 - H351
Precautionary statements	P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Codes	F,C
Risk Statements	11-14-19-34-37-40
Safety Statements	16-26-36/37/39-45
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	-4.0 °F
Flash Point(C)	-20 °C
Supplemental Hazard Statements	EUH014 - EUH018 - EUH019

bp	65-67 °C
Density	0.955 g/mL at 25 °C
UNSPSC	12352103

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