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1,1,1-Trimethylhydrazinium iodide

ALDRICH/471623 - 97%

Synonym: 1,1,1-Trimethylhydrazine iodide; N,N,N-Trimethylhydrazinium iodide; Trimethylhydrazonium iodide (6CI)

CAS Number: 3288-80-0
Empirical Formula (Hill Notation): C3H11IN2
Molecular Weight: 202.04
MDL Number: MFCD00464984
Linear Formula: H2NN(CH3)3I
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-471623-50G 50 g
 $0.00
1/EA
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 471623-50G

 

assay 97%
InChI 1S/C3H11N2.HI/c1-5(2,3)4;/h4H2,1-3H3;1H/q+1;/p-1
InChI key HLNPDVKKRBWQAA-UHFFFAOYSA-M
mp 225-230 °C (dec.) (lit.)
SMILES string [I-].C[N+](C)(C)N
Application: 1,1,1-Trimethylhydrazinium iodide (TMHI) may be employed for the amination of 1-X-3,5-dinitrobenzenes.
General description: 1,1,1-Trimethylhydrazinium iodide ([(CH3)3N-NH2]I, TMHI) is widely employed as a vicarious nucleophilic substitution (VNS) reagent for various aromatic amination reactions. On reaction with silver salt, it affords the following salts: nitrate (([(CH3)3N-NH2][NO3]), perchlorate ([(CH3)3N-NH2][ClO4]), azide ([(CH3)3N-NH2][N3]), 5-amino-1H-tetrazolate ([(CH3)3N-NH2][H2N-CN4]) and sulfate ([(CH3)3N-NH2]2[SO4].2H2O).
Packaging: 50 g in glass bottle
Purity 97%
mp 225-230 °C (dec.) (lit.)
UNSPSC 12352100

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