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(1,3-Dioxolan-2-ylmethyl)magnesium bromide solution

ALDRICH/472611 - 0.5 M in THF

Synonym: 2-[(Bromomagnesio)methyl]-1,3-dioxolane; Bromo(1,3-dioxolan-2-ylmethyl)magnesium

CAS Number: 180675-22-3
Empirical Formula (Hill Notation): C4H7BrMgO2
Molecular Weight: 191.31
MDL Number: MFCD01321271
Linear Formula: C4H7BrMgO2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-472611-100ML 100 mL
 $190.00
1/EA		 Add To Favorites
45-472611-1L 1 L
 $889.00
1/EA		 Add To Favorites

 

bp 65-67 °C
concentration 0.5 M in THF
density 0.938 g/mL at 25 °C
InChI 1S/C4H7O2.BrH.Mg/c1-4-5-2-3-6-4;;/h4H,1-3H2;1H;/q;;+1/p-1
InChI key ZDNTZRAFJZERSL-UHFFFAOYSA-M
reaction suitability reaction type: Grignard Reaction
SMILES string Br[Mg]CC1OCCO1
Application: (1,3-Dioxolan-2-ylmethyl)magnesium bromide is a Grignard reagent that can be used to prepare:
• 3-[11C]-Propionaldehyde, a key intermediate for the synthesis of radiolabeled compound [11C]SN-38, wherein SN-38 is 7-ethyl-10-hydroxy camptothecin.
• 1-[(S)-2,2-Dimethyl-(1,3)-dioxolan-4-yl]-4-(1,3-dioxolan2-yl)-2-ol by reacting with D-glyceraldehyde, which is further used to synthesize unsaturated nucleosides.
• A bicyclo carboxylate intermediate, which is employed in the total synthesis of spirovibsanin A.
Packaging: 1 L in Sure/Seal™
Packaging: 100 mL in Sure/Seal™
bp 65-67 °C
Density 0.938 g/mL at 25 °C
UNSPSC 12352103

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