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(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)

ALDRICH/474606

Synonym: (S,S)-Co(salen); (S,S)-Jacobsen HKR catalyst

CAS Number: 188264-84-8
Empirical Formula (Hill Notation): C36H52CoN2O2
Molecular Weight: 603.74
MDL Number: MFCD01631278
Linear Formula: [[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]Co
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-474606-1G 1 g
 $57.60
1/EA		 Add To Favorites
45-474606-5G 5 g
 $193.00
1/EA		 Add To Favorites

 

InChI 1S/C36H54N2O2.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;/h17-22,29-30,39-40H,13-16H2,1-12H3;/q;+2/p-2/b37-21+,38-22+;/t29-,30-;/m0./s1
InChI key ZFWPDJKMASHRPT-IKKUFEJKSA-L
mp >350 °C (lit.)
Quality Level 200 
SMILES string CC(C)(C)c1cc2C=[N@@H]3[C@H]4CCCC[C@@H]4[N@H]5=Cc6cc(cc(c6O[Co]35Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
Application: (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) may be used as a catalyst for the Jacobsen′s hydrolytic kinetic resolution of racemic epoxides, which is a key step during the multi-step synthesis of (+)-patulolide C, macrosphelides(I and G), (-)-(3S,6R)-3,6-dihydroxy-10-methylundecanoic acid, dodoneine, epidodoneine and protein kinase C epsilon (PKCe) inhibitors.
Application: Catalyst for the hydrolytic kinetic resolution of terminal epoxides and the enantioselective ring opening of meso epoxides.
Legal Information: Sold under license from Sterling Pharma Solutions Limited.
Packaging: 1, 5, 25 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
mp >350 °C (lit.)
UNSPSC 12352001

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