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Tin(II) chloride dihydrate

ALDRICH/474762 - ≥99.97% trace metals basis

Synonym: Stannous dichloride dihydrate; Stannous chloride dihydrate

CAS Number: 10025-69-1
Empirical Formula (Hill Notation): Cl2Sn · 2H2O
Molecular Weight: 225.65
EC Number: 231-868-0
MDL Number: MFCD00149863
Linear Formula: SnCl2 · 2H2O
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-474762-5G 5 g
$81.00
1/EA
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45-474762-25G 25 g
$204.00
1/EA
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assay ≥99.97% trace metals basis
bp 652 °C (lit.)
InChI 1S/2ClH.2H2O.Sn/h2*1H;2*1H2;/q;;;;+2/p-2
InChI key FWPIDFUJEMBDLS-UHFFFAOYSA-L
mp 37-38 °C (dec.) (lit.)
Quality Level 100 
reaction suitability core: tin
  reagent type: catalyst
SMILES string O.O.Cl[SnH2]Cl
Application: Tin(II) chloride dihydrate can be used as a mild Lewis acid catalyst to synthesize:      
• 3-Aminoimidazo[1,2-a]pyridines via three-component condensation reaction of aromatic aldehydes, 2-aminopyridines, and isonitriles.     
• Pyrazolo[5,4-b]quinoline derivatives via cyclocondensation reaction of 5-amino-3-(arylamino)-1H-pyrazole-4-carbonitriles with cyclohexane-1,3-dione or dimedone.    
• Polylactic acid from aqueous lactic acid in the presence of succinic anhydride.

It can also be used as a cocatalyst to synthesize indole derivatives by treating anilines with trialkanolamines in the presence of ruthenium as a catalyst.
Packaging: 5, 25 g in poly bottle
Purity ≥99.97% trace metals basis
bp 652 °C (lit.)
mp 37-38 °C (dec.) (lit.)
UNSPSC 12161600

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