3-Methyl-2-oxindole

ALDRICH/493937 - 96%

Synonym: 3-Methyloxindole

CAS Number: 1504-06-9
Empirical Formula (Hill Notation): C₉H₉NO
Molecular Weight: 147.17
MDL Number: MFCD04037370
Linear Formula: C₉H₉NO
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-493937-5G	5 g	$0.00 1/EA CALL FOR PRICE		Add To Favorites
45-493937-25G	25 g	$346.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	96%
form	solid
InChI	1S/C9H9NO/c1-6-7-4-2-3-5-8(7)10-9(6)11/h2-6H,1H3,(H,10,11)
InChI key	BBZCPUCZKLTAJQ-UHFFFAOYSA-N
mp	117-121 °C (lit.)
SMILES string	CC1C(=O)Nc2ccccc12

Application:	• Reactant for enantioselective α-amination reactions • Reactant for aldol reaction with glyoxal derivatives • Reactant for amine thiourea catalyzed conjugate addition to α,β-unsaturated aldehydes • Reactant for O-acetylation reactions • Reactant for preparation of a disubstituted oxoindole by using rhodium-catalyzed cyclopropanation/ring-opening reactions
Application:	3-Methyl-2-oxindole may be used in the preparation of 3-hydroxy-3-methyl-2-oxindole.
General description:	3-Methyl-2-oxindole (MOI) is a 3-substituted-2-oxindole. It is reported to be formed during the oxidation of indole-3-acetic acid in the presence of Fe^II under aerobic conditions. MOI undergoes asymmetric anti-Mannich-type reaction with N-tosyl aryl aldimines in the presence of alkaloid cinchona derivatives to form anti-3,3-disubsituted 2-oxindole derivatives. It also undergoes asymmetric hydroxyamination with nitrosoarenes to form N-nitroso aldol products.
Packaging:	5, 25 g in glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	96%
mp	117-121 °C (lit.)
UNSPSC	12352100

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